{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T15:36:00Z","timestamp":1785425760982,"version":"3.56.0"},"reference-count":25,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2026,1,1]],"date-time":"2026-01-01T00:00:00Z","timestamp":1767225600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,1,1]],"date-time":"2026-01-01T00:00:00Z","timestamp":1767225600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2025,12,12]]},"published-print":{"date-parts":[[2026,1,1]]},"abstract":"<jats:p>\n                    The title complex, [Co(C\n                    <jats:sub>8<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>7<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ], crystallizes in the monoclinic space group\n                    <jats:italic>P2<\/jats:italic>\n                    <jats:sub>1<\/jats:sub>\n                    <jats:italic>\/c<\/jats:italic>\n                    with one-half of the molecule in the asymmetric unit. The Co\n                    <jats:sup>2+<\/jats:sup>\n                    ion exhibits a distorted octahedral environment formed by two monodentate benzimidazole ligands and two bidentate benzimidazole-2-carboxylate ligands. The crystal packing features N\u2014H...O hydrogen bonds and C\u2014H...\u03c0 contacts, which generate a chain along [011]. Hirshfeld surface analysis shows that H...C\/C...H (36.2%) and H...H (35.3%) contacts dominate the intermolecular interactions, followed by O...H\/H...O and N...H\/H...N contributions.\n                  <\/jats:p>","DOI":"10.1107\/s2056989025011211","type":"journal-article","created":{"date-parts":[[2025,12,16]],"date-time":"2025-12-16T16:46:09Z","timestamp":1765903569000},"page":"91-95","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis, crystal structure and Hirshfeld surface analysis of bis(1\n                    <i>H<\/i>\n                    -benzimidazole-\u03ba\n                    <i>N<\/i>\n                    <sup>3<\/sup>\n                    )bis(benzimidazole-2-carboxylato-\u03ba\n                    <sup>2<\/sup>\n                    <i>N<\/i>\n                    <sup>3<\/sup>\n                    ,\n                    <i>O<\/i>\n                    )cobalt(II)"],"prefix":"10.1107","volume":"82","author":[{"given":"Farangiz","family":"Khujayeva","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-2721-6678","authenticated-orcid":true,"given":"Sardor","family":"Murodov","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rukhshona","family":"Muratkulova","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Soliha","family":"Rixsiboyeva","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5741-6347","authenticated-orcid":true,"given":"Kambarali","family":"Turgunov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3027-9893","authenticated-orcid":true,"given":"Bakhodir","family":"Tashkhodjaev","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2606-3221","authenticated-orcid":true,"given":"Shakhlo","family":"Daminova","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,1,1]]},"reference":[{"key":"jp2023_bb1","doi-asserted-by":"crossref","first-page":"6208","DOI":"10.1016\/j.bmc.2012.09.013","volume":"20","author":"Bansal","year":"2012","journal-title":"Bioorg. 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