{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,5]],"date-time":"2026-02-05T22:25:46Z","timestamp":1770330346881,"version":"3.49.0"},"reference-count":11,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2026,1,20]],"date-time":"2026-01-20T00:00:00Z","timestamp":1768867200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,1,20]],"date-time":"2026-01-20T00:00:00Z","timestamp":1768867200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"crossref","award":["RS-2024\u201300446825"],"award-info":[{"award-number":["RS-2024\u201300446825"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,1,8]]},"published-print":{"date-parts":[[2026,2,1]]},"abstract":"<jats:p>\n                    The synthesis and crystal structure of an unprecedented compound, zinc phosphorus heptachloride or\n                    <jats:italic>catena<\/jats:italic>\n                    -poly[phosphorus tetrachloride [[dichloridozinc]-\u03bc-chlorido]], ZnPCl\n                    <jats:sub>7<\/jats:sub>\n                    or {[PCl\n                    <jats:sub>4<\/jats:sub>\n                    ][ZnCl\n                    <jats:sub>3<\/jats:sub>\n                    ]}\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    , are reported. The reaction of ZnCl\n                    <jats:sub>2<\/jats:sub>\n                    with PCl\n                    <jats:sub>5<\/jats:sub>\n                    in a 1:1 molar ratio at 623\u2005K produced single crystals of ZnPCl\n                    <jats:sub>7<\/jats:sub>\n                    , which crystallizes in the orthorhombic space group\n                    <jats:italic>Ama2<\/jats:italic>\n                    . The Zn and P atoms lie on crystallographic mirror planes, as do four of the Cl atoms. One Cl atom lies on a twofold axis and one occupies a general position. Its extended structure features isolated [PCl\n                    <jats:sub>4<\/jats:sub>\n                    ]\n                    <jats:sup>+<\/jats:sup>\n                    tetrahedra and one-dimensional chains of corner-sharing ZnCl\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>2\/2<\/jats:sub>\n                    tetrahedra. Bond-valence sum calculations support the assignment of formal oxidation states. This discovery extends the compositional and structural landscape of mixed-metal halides.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026000174","type":"journal-article","created":{"date-parts":[[2026,1,12]],"date-time":"2026-01-12T07:04:53Z","timestamp":1768201493000},"page":"191-193","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["ZnPCl\n                    <sub>7<\/sub>\n                    : a compositionally and structurally unprecedented metal\u2013phosphorus halide"],"prefix":"10.1107","volume":"82","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9469-4565","authenticated-orcid":true,"given":"Hyeonjin","family":"Seo","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5768-121X","authenticated-orcid":true,"given":"Seung-Tae","family":"Hong","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2026,1,20]]},"reference":[{"key":"hb8172_bb1","doi-asserted-by":"crossref","first-page":"1487","DOI":"10.1107\/S0021889803021800","volume":"36","author":"Betteridge","year":"2003","journal-title":"J. Appl. Cryst."},{"key":"hb8172_bb2","unstructured":"Bruker (2006). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"hb8172_bb3","doi-asserted-by":"crossref","first-page":"18","DOI":"10.1107\/S2052520618015718","volume":"75","author":"Chen","year":"2019","journal-title":"Acta Cryst. B"},{"key":"hb8172_bb4","first-page":"0010","volume":"474","author":"Chen","year":"2023","journal-title":"Coord. Chem. Rev."},{"key":"hb8172_bb5","doi-asserted-by":"crossref","first-page":"7188","DOI":"10.1021\/cm801723b","volume":"20","author":"D'Hondt","year":"2008","journal-title":"Chem. Mater."},{"key":"hb8172_bb7","doi-asserted-by":"crossref","first-page":"1272","DOI":"10.1107\/S0021889811038970","volume":"44","author":"Momma","year":"2011","journal-title":"J. Appl. Cryst."},{"key":"hb8172_bb12","doi-asserted-by":"crossref","unstructured":"Otwinowski, Z. & Minor, W. (1997). Methods in Enzymology, Vol. 276, Macromolecular Crystallography, Part A, edited by C. W. Carter Jr & R. M. Sweet, pp. 307-326. New York: Academic Press.","DOI":"10.1016\/S0076-6879(97)76066-X"},{"key":"hb8172_bb8","doi-asserted-by":"crossref","first-page":"786","DOI":"10.1107\/S0021889807029238","volume":"40","author":"Palatinus","year":"2007","journal-title":"J. Appl. Cryst."},{"key":"hb8172_bb13","doi-asserted-by":"crossref","first-page":"249","DOI":"10.1107\/S2052519213010014","volume":"69","author":"Parsons","year":"2013","journal-title":"Acta Cryst. B"},{"key":"hb8172_bb10","doi-asserted-by":"crossref","first-page":"751","DOI":"10.1107\/S0567739476001551","volume":"32","author":"Shannon","year":"1976","journal-title":"Acta Cryst. A"},{"key":"hb8172_bb11","doi-asserted-by":"crossref","unstructured":"Winkler, H. & Brehler, B. (1959). Naturwissenschaften pp. 553-554.","DOI":"10.1007\/BF00631282"}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2026\/02\/00\/hb8172\/hb8172.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2026\/02\/00\/hb8172\/hb8172.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,2,5]],"date-time":"2026-02-05T10:24:32Z","timestamp":1770287072000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989026000174"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,1,20]]},"references-count":11,"journal-issue":{"issue":"2","published-online":{"date-parts":[[2026,2]]}},"alternative-id":["S2056989026000174"],"URL":"https:\/\/doi.org\/10.1107\/s2056989026000174","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989026000174\/hb8172sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989026000174\/hb8172Isup2.hkl","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"value":"2056-9890","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,1,20]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?hb8172","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"3 November 2025","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"8 January 2026","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"20 January 2026","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?hb8172"}},{"value":"\u00a9 2026 Seo and Hong","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}