{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T09:35:59Z","timestamp":1785404159863,"version":"3.56.0"},"reference-count":23,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2026,1,16]],"date-time":"2026-01-16T00:00:00Z","timestamp":1768521600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,1,16]],"date-time":"2026-01-16T00:00:00Z","timestamp":1768521600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"Department of Biotechnology (DBT), New Delhi, India","award":["BT\/PR36476\/NNT\/28\/1723\/2020"],"award-info":[{"award-number":["BT\/PR36476\/NNT\/28\/1723\/2020"]}]},{"name":"DST-FIST, India","award":["SR\/FST\/CS-1\/2021\/215"],"award-info":[{"award-number":["SR\/FST\/CS-1\/2021\/215"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,1,9]]},"published-print":{"date-parts":[[2026,2,1]]},"abstract":"<jats:p>\n                    In the title compound, [Cu(C\n                    <jats:sub>11<\/jats:sub>\n                    H\n                    <jats:sub>15<\/jats:sub>\n                    N\n                    <jats:sub>3<\/jats:sub>\n                    S\n                    <jats:sub>2<\/jats:sub>\n                    ){P(C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    }\n                    <jats:sub>2<\/jats:sub>\n                    ]NO\n                    <jats:sub>3<\/jats:sub>\n                    \u00b7CCl\n                    <jats:sub>4<\/jats:sub>\n                    , the carbon tetrachloride solvent molecule is presumed to have originated as an impurity in the chloroform solvent used. The coordination environment around the copper(I) ion is a distorted CuNSP\n                    <jats:sub>2<\/jats:sub>\n                    tetrahedron, with a \u03c4\n                    <jats:sub>4<\/jats:sub>\n                    structural index of 0.844. In the extended structure, the cation and anion are linked by an N\u2014H...O hydrogen bond. Along with electrostatic forces, C\u2014H...N, C\u2014H...S and C\u2014H...O hydrogen bonds help to consolidate the crystal packing.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026000228","type":"journal-article","created":{"date-parts":[[2026,1,12]],"date-time":"2026-01-12T16:37:22Z","timestamp":1768235842000},"page":"168-172","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Synthesis and structure of {methyl (\n                    <i>Z<\/i>\n                    )-2-[4-(dimethylamino)benzylidene]hydrazine-1-carbodithioate-\u03ba\n                    <sup>2<\/sup>\n                    <i>N<\/i>\n                    <sup>2<\/sup>\n                    ,\n                    <i>S<\/i>\n                    }bis(triphenylphosphine-\u03ba\n                    <i>P<\/i>\n                    )copper(I) nitrate carbon tetrachloride monosolvate"],"prefix":"10.1107","volume":"82","author":[{"given":"Liji","family":"Muthirakalayil Abraham","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03ytqnm28","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Banmankhraw","family":"Dkhar","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/055m2tx54","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Amirthalingam","family":"Arunkumar","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03ytqnm28","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thangaraja","family":"Chinnathangavel","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kolandaivelu","family":"Saminathan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6488-8000","authenticated-orcid":true,"given":"Marappan","family":"Velusamy","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/055m2tx54","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2561-8387","authenticated-orcid":true,"given":"Venugopal","family":"Rajendiran","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03ytqnm28","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,1,16]]},"reference":[{"key":"hb8181_bb1","doi-asserted-by":"crossref","first-page":"C27","DOI":"10.1016\/0022-328X(83)87031-4","volume":"255","author":"Bianchini","year":"1983","journal-title":"J. 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