{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,6]],"date-time":"2026-11-06T23:59:34Z","timestamp":1794009574358,"version":"4.8.0"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2026,2,13]],"date-time":"2026-02-13T00:00:00Z","timestamp":1770940800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,2,13]],"date-time":"2026-02-13T00:00:00Z","timestamp":1770940800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,2,3]]},"published-print":{"date-parts":[[2026,3,1]]},"abstract":"<jats:p>\n                    In the title salt, (C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    N\n                    <jats:sub>3<\/jats:sub>\n                    S)\n                    <jats:sub>2<\/jats:sub>\n                    [MnCl\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    )(H\n                    <jats:sub>2<\/jats:sub>\n                    O)\n                    <jats:sub>2<\/jats:sub>\n                    ], the central Mn\n                    <jats:sup>II<\/jats:sup>\n                    atom of the complex anion adopts a distorted octahedral coordination environment, defined by two aqua, two chlorido, and one bidentate malonato ligands. The anion is charge balanced by two thiadiazole moieties protonated at one of the heterocyclic N atoms. In the crystal, the cations and anions engage in extensive hydrogen-bonding interactions and short S...Cl contacts; additional \u03c0\u2013\u03c0 stacking interactions are present between adjacent cations. Hirshfeld surface analysis was used to quantify the intermolecular interactions of the complex anion, revealing that H...O, H...Cl, and H...H interactions contribute most to the crystal packing.\n                  <\/jats:p>","DOI":"10.1107\/s205698902600112x","type":"journal-article","created":{"date-parts":[[2026,2,4]],"date-time":"2026-02-04T06:40:37Z","timestamp":1770187237000},"page":"282-285","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Synthesis, crystal structure and Hirshfeld surface analysis of bis(2-amino-1,3,4-thiadiazol-3-ium) diaquadichlorido(propanedioato-\u03ba\n                    <sup>2<\/sup>\n                    <i>O<\/i>\n                    <sup>1<\/sup>\n                    ,\n                    <i>O<\/i>\n                    <sup>3<\/sup>\n                    )manganate(II)"],"prefix":"10.1107","volume":"82","author":[{"given":"Guzal","family":"Nuralieva","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mushtari","family":"Alieva","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ekaterina","family":"Kinshakova","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aziz","family":"Atashov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4441-2803","authenticated-orcid":true,"given":"Jamshid","family":"Ashurov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0084-7653","authenticated-orcid":true,"given":"Shakhnoza","family":"Kadirova","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9218-5596","authenticated-orcid":true,"given":"Batirbay","family":"Torambetov","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,2,13]]},"container-title":["Acta Crystallographica Section E Crystallographic 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(CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}