{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,8]],"date-time":"2026-04-08T05:04:21Z","timestamp":1775624661668,"version":"3.50.1"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2026,2,24]],"date-time":"2026-02-24T00:00:00Z","timestamp":1771891200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,2,24]],"date-time":"2026-02-24T00:00:00Z","timestamp":1771891200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,2,6]]},"published-print":{"date-parts":[[2026,3,1]]},"abstract":"<jats:p>\n                    The title compound (\n                    <jats:italic>E<\/jats:italic>\n                    )-2-(benzo[\n                    <jats:italic>d<\/jats:italic>\n                    ]thiazol-2-yl)-\n                    <jats:italic>N<\/jats:italic>\n                    \u2032-(1-(4-bromophenyl)ethylidene)acetohydrazide, C\n                    <jats:sub>17<\/jats:sub>\n                    H\n                    <jats:sub>14<\/jats:sub>\n                    BrN\n                    <jats:sub>3<\/jats:sub>\n                    OS, crystallizes in space group\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>c<\/jats:italic>\n                    with\n                    <jats:italic>Z<\/jats:italic>\n                    = 4. The configuration across the formal N=C double bond at the hydrazide moiety is\n                    <jats:italic>E<\/jats:italic>\n                    ; the atom sequence C\u2014C\u2014C(= O)\u2014N\u2014N=C\u2014(bromophenyl) is very approximately planar (r.m.s. deviation 0.17\u2005\u00c5, when all carbon atoms of the bromophenyl group are included), being synperiplanar around the C(=O)\u2014N bond and antiperiplanar (choosing the appropriate final atom C\n                    <jats:sub>Ar<\/jats:sub>\n                    ) elsewhere. The interplanar angle to the benzothiazole unit (r.m.s. deviation 0.01\u2005\u00c5) is 69.75\u2005(2)\u00b0. The main packing feature is a classical inversion-symmetric dimer with hydrogen bonds of the type N\u2014H...O=C. This combines with a rather long N\n                    <jats:sub>thiazole<\/jats:sub>\n                    ...Br halogen bond to form a thick layer structure parallel to the\n                    <jats:italic>bc<\/jats:italic>\n                    plane.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026001313","type":"journal-article","created":{"date-parts":[[2026,2,10]],"date-time":"2026-02-10T14:00:46Z","timestamp":1770732046000},"page":"293-296","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Synthesis and crystal structure of 2-(benzo[\n                    <i>d<\/i>\n                    ]thiazol-2-yl)-\n                    <i>N<\/i>\n                    \u2032-[(\n                    <i>E<\/i>\n                    )-1-(4-bromophenyl)ethylidene]acetohydrazide"],"prefix":"10.1107","volume":"82","author":[{"given":"Heba A.","family":"Elboshi","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6807-2110","authenticated-orcid":true,"given":"Rasha A.","family":"Azzam","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Galal H.","family":"Elgemeie","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Peter G.","family":"Jones","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2026,2,24]]},"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2026\/03\/00\/yz2073\/yz2073.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2026\/03\/00\/yz2073\/yz2073.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,5]],"date-time":"2026-03-05T11:19:14Z","timestamp":1772709554000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989026001313"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,2,24]]},"references-count":0,"journal-issue":{"issue":"3","published-online":{"date-parts":[[2026,3]]}},"alternative-id":["S2056989026001313"],"URL":"https:\/\/doi.org\/10.1107\/s2056989026001313","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989026001313\/yz2073sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989026001313\/yz2073Isup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989026001313\/yz2073Isup3.cml","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"value":"2056-9890","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,2,24]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?yz2073","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"27 January 2026","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"6 February 2026","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"24 February 2026","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?yz2073"}},{"value":"\u00a9 2026 Elboshi\n                      et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}