{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,6]],"date-time":"2026-06-06T02:47:08Z","timestamp":1780714028618,"version":"3.54.1"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2026,2,24]],"date-time":"2026-02-24T00:00:00Z","timestamp":1771891200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,2,24]],"date-time":"2026-02-24T00:00:00Z","timestamp":1771891200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,2,19]]},"published-print":{"date-parts":[[2026,3,1]]},"abstract":"<jats:p>\n                    Crystals of the title compound, [Cu(NCS)(C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )]\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    (C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    = 2,6-dimethylpyrazine), were prepared by the reaction of CuNCS and 2,6-dimethylpyrazine in acetonitrile. The asymmetric unit consists of one Cu\n                    <jats:sup>I<\/jats:sup>\n                    cation, one thiocyanate anion and one 2,6-dimethylpyrazine ligand with all atoms lying on general positions. The copper cations are tetrahedrally coordinated by two S- and one N-bonded thiocyanate anions and one 2,6-dimethylpyrazine ligand, which s  coordinated to the metal center with the N atom that is not adjacent to the methyl groups. The copper cations are linked by the \u03bc-1,3,3 (\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>S<\/jats:italic>\n                    ,\n                    <jats:italic>S<\/jats:italic>\n                    ) bridging thiocyanate anions into layers that lie parallel to the\n                    <jats:italic>ac<\/jats:italic>\n                    plane. The layers are stacked perpendicular to the\n                    <jats:italic>b<\/jats:italic>\n                    -axis direction and are separated by the 2,6-dimethylpyrazine ligands. The title crystal structure is compared with those of related CuNCS compounds with isomeric dimethylpyrazine ligands.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026001866","type":"journal-article","created":{"date-parts":[[2026,2,24]],"date-time":"2026-02-24T09:09:13Z","timestamp":1771924153000},"page":"305-308","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Synthesis and crystal structure of poly[(2,6-dimethylpyrazine-\u03ba\n                    <i>N<\/i>\n                    <sup>4<\/sup>\n                    )(\u03bc\n                    <sub>3<\/sub>\n                    -thiocyanato-\u03ba\n                    <sup>3<\/sup>\n                    <i>N<\/i>\n                    :\n                    <i>S<\/i>\n                    :\n                    <i>S<\/i>\n                    )copper(I)]"],"prefix":"10.1107","volume":"82","author":[{"given":"Christian","family":"N\u00e4ther","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,2,24]]},"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2026\/03\/00\/hb8197\/hb8197.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2026\/03\/00\/hb8197\/hb8197.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,5]],"date-time":"2026-03-05T11:19:16Z","timestamp":1772709556000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989026001866"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,2,24]]},"references-count":0,"journal-issue":{"issue":"3","published-online":{"date-parts":[[2026,3]]}},"alternative-id":["S2056989026001866"],"URL":"https:\/\/doi.org\/10.1107\/s2056989026001866","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989026001866\/hb8197sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989026001866\/hb8197Isup2.hkl","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"value":"2056-9890","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,2,24]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?hb8197","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"17 February 2026","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"19 February 2026","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"24 February 2026","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?hb8197"}},{"value":"\u00a9 2026 Christian N\u00e4ther","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}