{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T09:57:19Z","timestamp":1785405439209,"version":"3.56.0"},"reference-count":20,"publisher":"International Union of Crystallography (IUCr)","issue":"4","license":[{"start":{"date-parts":[[2026,3,24]],"date-time":"2026-03-24T00:00:00Z","timestamp":1774310400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,3,24]],"date-time":"2026-03-24T00:00:00Z","timestamp":1774310400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,2,19]]},"published-print":{"date-parts":[[2026,4,1]]},"abstract":"<jats:p>\n                    The title compound, [Pd(C\n                    <jats:sub>20<\/jats:sub>\n                    H\n                    <jats:sub>31<\/jats:sub>\n                    ClNS\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ], crystallizes about an inversion centre in the monoclinic space group\n                    <jats:italic>C<\/jats:italic>\n                    2\/\n                    <jats:italic>c<\/jats:italic>\n                    . The Pd\n                    <jats:sup>II<\/jats:sup>\n                    cation adopts a square-planar coordination geometry defined by four sulfur atoms from two\n                    <jats:italic>N<\/jats:italic>\n                    -(4-chlorobenzyl)-\n                    <jats:italic>N<\/jats:italic>\n                    -dodecyldithiocarbamate anions. The crystal packing features C\u2014H...S hydrogen bonds, which form a belt motif. Hirshfeld surface analysis indicates that H...H (62.9%), S...H\/H...S (14.0%) and Cl...H\/H...Cl (11.1%) contacts dominate the intermolecular interactions.\n                  <\/jats:p>","DOI":"10.1107\/s205698902600188x","type":"journal-article","created":{"date-parts":[[2026,3,19]],"date-time":"2026-03-19T13:58:37Z","timestamp":1773928717000},"page":"384-387","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis, crystal structure and Hirshfeld surface analysis of bis[\n                    <i>N<\/i>\n                    -(4-chlorobenzyl)-\n                    <i>N<\/i>\n                    -dodecyldithiocarbamato-\u03ba\n                    <sup>2<\/sup>\n                    <i>S<\/i>\n                    ,\n                    <i>S<\/i>\n                    \u2032]palladium(II)"],"prefix":"10.1107","volume":"82","author":[{"given":"R.","family":"Pallavi","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/01x24z140","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"N.","family":"Srinivasan","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/0034me914","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"S.","family":"Thirumaran","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/01x24z140","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,3,24]]},"reference":[{"key":"ex2098_bb1","doi-asserted-by":"crossref","first-page":"1317","DOI":"10.3390\/ijms23031317","volume":"23","author":"Ajiboye","year":"2022","journal-title":"Int. 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