{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,6]],"date-time":"2026-05-06T12:21:24Z","timestamp":1778070084482,"version":"3.51.4"},"reference-count":22,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2026,4,17]],"date-time":"2026-04-17T00:00:00Z","timestamp":1776384000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,4,17]],"date-time":"2026-04-17T00:00:00Z","timestamp":1776384000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,3,26]]},"published-print":{"date-parts":[[2026,5,1]]},"abstract":"<jats:p>\n                    The title compound, C\n                    <jats:sub>14<\/jats:sub>\n                    H\n                    <jats:sub>13<\/jats:sub>\n                    ClN\n                    <jats:sub>4<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>2<\/jats:sub>\n                    \u00b7C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    OS, crystallizes in space group\n                    <jats:italic>P<\/jats:italic>\n                    <jats:overline>1<\/jats:overline>\n                    with\n                    <jats:italic>Z<\/jats:italic>\n                    = 4. Both main (\u2018parent') molecules are closely similar except for minor differences in the orientations of the aromatic rings. The bond angles at the nitrogen atoms of the (S)C\u2014NH\u2014C\n                    <jats:sub>guanidine<\/jats:sub>\n                    moieties are very wide at\n                    <jats:italic>ca<\/jats:italic>\n                    130\u00b0. The parent molecules display intramolecular hydrogen bonds Ph\u2014N\u2014H...N\u2014S and C\u2014N(H)\u2014H...O=S, and both formula units involve a bifurcated hydrogen bond system from two N\u2014H donors to the oxygen atom of a DMSO molecule; the orientation of the DMSO molecules is however appreciably different. Further classical hydrogen bonds link the residues to form a ribbon parallel to the\n                    <jats:italic>b<\/jats:italic>\n                    axis.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026003245","type":"journal-article","created":{"date-parts":[[2026,3,26]],"date-time":"2026-03-26T16:53:38Z","timestamp":1774544018000},"page":"485-489","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and crystal structure of 1-{\n                    <i>N<\/i>\n                    \u2032-[(4-chlorobenzene)sulfonyl]carbamimidoyl}-3-phenylthiourea dimethyl sulfoxide monosolvate"],"prefix":"10.1107","volume":"82","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6388-5350","authenticated-orcid":true,"given":"Reham A.","family":"Mohamed-Ezzat","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Galal H.","family":"Elgemeie","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Peter G.","family":"Jones","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2026,4,17]]},"reference":[{"key":"yz2076_bb1","unstructured":"Bruker (1998). 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