{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,6]],"date-time":"2026-05-06T12:21:24Z","timestamp":1778070084447,"version":"3.51.4"},"reference-count":29,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2026,4,14]],"date-time":"2026-04-14T00:00:00Z","timestamp":1776124800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,4,14]],"date-time":"2026-04-14T00:00:00Z","timestamp":1776124800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,4,8]]},"published-print":{"date-parts":[[2026,5,1]]},"abstract":"<jats:p>\n                    Unlike typical hexahydrates, the title compound, [Mg(C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    O)\n                    <jats:sub>2<\/jats:sub>\n                    (H\n                    <jats:sub>2<\/jats:sub>\n                    O)\n                    <jats:sub>4<\/jats:sub>\n                    ]Br\n                    <jats:sub>2<\/jats:sub>\n                    \u00b72C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    O or [Mg(H\n                    <jats:sub>2<\/jats:sub>\n                    O)\n                    <jats:sub>4<\/jats:sub>\n                    (DME)\n                    <jats:sub>2<\/jats:sub>\n                    ]Br\n                    <jats:sub>2<\/jats:sub>\n                    \u00b7DME\n                    <jats:sub>2<\/jats:sub>\n                    (DME = dimethyl ether, C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    O), is a water-poor magnesium(II) complex. The central magnesium cation (site symmetry\n                    <jats:overline>1<\/jats:overline>\n                    ) is coordinated by four water molecules and two molecules of dimethyl ether and adopts a slightly elongated\n                    <jats:italic>trans<\/jats:italic>\n                    -octahedral coordination geometry. The water molecules are linked to outer-sphere bromide anions and additional dimethyl ether molecules\n                    <jats:italic>via<\/jats:italic>\n                    O\u2014H...Br and O\u2014H...O hydrogen bonds. Due to the volatility of dimethyl ether, the presence of coordinating and non-coordinating molecules of this ether makes this solid state structure presented here particularly interesting. To investigate the intermolecular interactions leading to this special coordination, a Hirshfeld surface analysis was performed. It showed that the H...H interactions (70.4%) make the largest contribution to the crystal packing, followed by H...Br interactions (19.4%), H...O interactions (10.1%) and Br...O interactions (0.1%).\n                  <\/jats:p>","DOI":"10.1107\/s205698902600366x","type":"journal-article","created":{"date-parts":[[2026,4,9]],"date-time":"2026-04-09T06:41:48Z","timestamp":1775716908000},"page":"463-466","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and structure of tetraaquabis(dimethyl ether)magnesium(II) dibromide dimethyl ether disolvate"],"prefix":"10.1107","volume":"82","author":[{"given":"Beata","family":"Moritz","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tristan","family":"Mairath","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4787-2135","authenticated-orcid":true,"given":"Carsten","family":"Strohmann","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2026,4,14]]},"reference":[{"key":"hb8210_bb1","first-page":"2S1","author":"Allen","year":"1987","journal-title":"J. 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