{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T06:18:09Z","timestamp":1788329889474,"version":"build-2803163510"},"reference-count":31,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2026,5,7]],"date-time":"2026-05-07T00:00:00Z","timestamp":1778112000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,5,7]],"date-time":"2026-05-07T00:00:00Z","timestamp":1778112000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100002673","name":"Academy of Sciences of the Republic of Uzbekistan","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100002673","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,4,29]]},"published-print":{"date-parts":[[2026,6,1]]},"abstract":"<jats:p>\n                    In the presence of trimethylamine, new compounds were obtained by arylsulfonylation of 3-(piperidin-2-yl)pyridine (the alkaloid anabasine), namely: (\n                    <jats:italic>S<\/jats:italic>\n                    )-3-{1-[(4-chlorophenyl)sulfonyl]piperidin-2-yl}pyridine, C\n                    <jats:sub>16<\/jats:sub>\n                    H\n                    <jats:sub>17<\/jats:sub>\n                    ClN\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    S (\n                    <jats:bold>1<\/jats:bold>\n                    ); (\n                    <jats:italic>S<\/jats:italic>\n                    )-3-[1-(4-methylphenyl)piperidin-2-yl]pyridine, C\n                    <jats:sub>17<\/jats:sub>\n                    H\n                    <jats:sub>20<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    S (\n                    <jats:bold>2<\/jats:bold>\n                    ); (\n                    <jats:italic>S<\/jats:italic>\n                    )-3-{1-[(4-methoxyphenyl)sulfonyl]piperidin-2-yl}pyridine, C\n                    <jats:sub>17<\/jats:sub>\n                    H\n                    <jats:sub>20<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    S (\n                    <jats:bold>3<\/jats:bold>\n                    ); and (\n                    <jats:italic>S<\/jats:italic>\n                    )-3-{1-[(3,4-dimethylphenyl)sulfonyl]piperidin-2-yl}pyridine, C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>22<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    S (\n                    <jats:bold>4<\/jats:bold>\n                    ). In the crystal structures, the spatial arrangement of the pyridine and piperidine rings around the C\n                    <jats:italic>sp<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    \u2014C* bond, as well as the orientation of the benzene ring of the arylsulfonyl group relative to the anabasine moiety, are analyzed.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026004524","type":"journal-article","created":{"date-parts":[[2026,4,29]],"date-time":"2026-04-29T16:18:31Z","timestamp":1777479511000},"page":"557-561","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structures of (\n                    <i>S<\/i>\n                    )-3-{1-[(4-chlorophenyl)sulfonyl]piperidin-2-yl}pyridine, (\n                    <i>S<\/i>\n                    )-3-[1-(4-methylphenyl)piperidin-2-yl]pyridine, (\n                    <i>S<\/i>\n                    )-3-{1-[(4-methoxyphenyl)sulfonyl]piperidin-2-yl}pyridine and (\n                    <i>S<\/i>\n                    )-3-{1-[(3,4-dimethylphenyl)sulfonyl]piperidin-2-yl}pyridine"],"prefix":"10.1107","volume":"82","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2154-0746","authenticated-orcid":true,"given":"R. 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