{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T06:18:15Z","timestamp":1788329895338,"version":"build-2803163510"},"reference-count":36,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2026,5,22]],"date-time":"2026-05-22T00:00:00Z","timestamp":1779408000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,5,22]],"date-time":"2026-05-22T00:00:00Z","timestamp":1779408000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/100006132","name":"U.S. Department of Energy, Office of Science","doi-asserted-by":"publisher","award":["DESC0025694"],"award-info":[{"award-number":["DESC0025694"]}],"id":[{"id":"10.13039\/100006132","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,5,13]]},"published-print":{"date-parts":[[2026,6,1]]},"abstract":"<jats:p>\n                    The title benzimidazole derivative, C\n                    <jats:sub>26<\/jats:sub>\n                    H\n                    <jats:sub>18<\/jats:sub>\n                    N\n                    <jats:sub>6<\/jats:sub>\n                    , which contains two benzimidazole units connected through an azo (N=N) linkage, was isolated as yellow needle-shaped crystals and characterized by single-crystal X-ray diffraction. The compound crystallizes in the monoclinic crystal system (space group:\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    <jats:italic>\/c<\/jats:italic>\n                    ) with one molecule in the asymmetric unit. The dominant interactions in the crystal are parallel \u03c0\u2013\u03c0 contacts, giving rise to one-dimensional \u03c0-stacks along the\n                    <jats:italic>a-<\/jats:italic>\n                    axis direction, with a centroid-to-centroid separation of 3.899\u2005(1)\u2005\u00c5, a slippage distance of 1.81\u2005\u00c5, and a slip angle of 27.61\u00b0. Within these stacks, two short C\u2014H...C contacts of 2.74\u2005\u00c5 are observed between adjacent molecules, which may reflect packing constraints. Along the\n                    <jats:italic>bc<\/jats:italic>\n                    plane, the structure comprises two-dimensional ribbons formed by antiparallel chains. No short interplanar contacts are observed between neighboring stacks.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026005098","type":"journal-article","created":{"date-parts":[[2026,5,22]],"date-time":"2026-05-22T07:43:21Z","timestamp":1779435801000},"page":"717-721","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Solid-state structure and supramolecular packing of 1,2-bis(2-phenyl-1\n                    <i>H<\/i>\n                    -benzo[\n                    <i>d<\/i>\n                    ]imidazol-1-yl)diazene"],"prefix":"10.1107","volume":"82","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6364-1102","authenticated-orcid":true,"given":"Christos P.","family":"Constantinides","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0004-4767-4114","authenticated-orcid":true,"given":"Jin-Seok","family":"Yi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1393-4868","authenticated-orcid":true,"given":"Simona","family":"Marincean","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,5,22]]},"reference":[{"key":"dx2069_bb1","doi-asserted-by":"crossref","first-page":"1809","DOI":"10.1039\/C1CS15179G","volume":"41","author":"Bandara","year":"2012","journal-title":"Chem. 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