{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T05:29:22Z","timestamp":1791264562561,"version":"4.1.0"},"reference-count":26,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2026,5,29]],"date-time":"2026-05-29T00:00:00Z","timestamp":1780012800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,5,29]],"date-time":"2026-05-29T00:00:00Z","timestamp":1780012800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,5,21]]},"published-print":{"date-parts":[[2026,6,1]]},"abstract":"<jats:p>\n                    Crystals of the title compound, {[CdBr\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )(H\n                    <jats:sub>2<\/jats:sub>\n                    O)]\u00b7C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    \u00b70.5H\n                    <jats:sub>2<\/jats:sub>\n                    O}\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    (C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    = 2,3-dimethylpyrazine), were obtained accidentally by the reaction of cadmium bromide with 2,3-dimethylpyrazine in water. The asymmetric unit consists of one Cd cation, two bromide anions, one 2,3-dimethylpyrazine ligand, one non-coordinating 2,3-dimethylpyrazine molecule, and one water molecule in general positions as well as an additional water molecule that is located on a twofold rotation axis. The cadmium cations are octahedrally coordinated by four bromide anions, one 2,3-dimethylpyrazine ligand and one water molecule, and are linked by pairs of \u03bc-1,1-bridging bromide anions into chains that propagate in the\n                    <jats:italic>a<\/jats:italic>\n                    -axis direction. These chains are further connected into layers by intermolecular hydrogen bonding. The coordinated water ligand is hydrogen bonded to the 2,3-dimethylpyrazine, and the water solvate molecule and the 2,3-dimethylpyrazine molecules of crystallization are linked by O\u2014H...N hydrogen bonding\n                    <jats:italic>via<\/jats:italic>\n                    the water solvate molecules into chains along the\n                    <jats:italic>c<\/jats:italic>\n                    -axis direction. The water solvate molecule therefore acts as donor for two O\u2014H...N and as acceptor for two O\u2014H...O hydrogen bonds.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026005372","type":"journal-article","created":{"date-parts":[[2026,5,29]],"date-time":"2026-05-29T05:46:36Z","timestamp":1780033596000},"page":"743-746","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Synthesis and crystal structure of\n                    <i>catena<\/i>\n                    -poly[[[aqua(2,3-dimethylpyrazine-\u03ba\n                    <i>N<\/i>\n                    )cadmium(II)]-di-\u03bc-bromido] 2,3-dimethylpyrazine monosolvate hemihydrate]"],"prefix":"10.1107","volume":"82","author":[{"given":"Christian","family":"N\u00e4ther","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,5,29]]},"reference":[{"key":"ev2028_bb24","doi-asserted-by":"crossref","first-page":"417","DOI":"10.1016\/0277-5387(96)00312-9","volume":"16","author":"Bailey","year":"1997","journal-title":"Polyhedron"},{"key":"ev2028_bb1","unstructured":"Brandenburg, K. 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