{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T20:13:48Z","timestamp":1792786428414,"version":"4.5.0"},"reference-count":31,"publisher":"International Union of Crystallography (IUCr)","issue":"7","license":[{"start":{"date-parts":[[2026,6,5]],"date-time":"2026-06-05T00:00:00Z","timestamp":1780617600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,6,5]],"date-time":"2026-06-05T00:00:00Z","timestamp":1780617600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"National Natural Science Foundation of China","award":["92361303"],"award-info":[{"award-number":["92361303"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,5,23]]},"published-print":{"date-parts":[[2026,7,1]]},"abstract":"<jats:p>\n                    The title compound, \u03bc\n                    <jats:sub>3<\/jats:sub>\n                    -chlorido-tri-\u03bc\n                    <jats:sub>3<\/jats:sub>\n                    -sulfido-tris(trimethylphosphine)[tris(3,5-dimethylpyrazol-1-yl)hydroborato]triiron(II)molybdenum(III) tetraphenylborate, [MoFe\n                    <jats:sub>3<\/jats:sub>\n                    S\n                    <jats:sub>3<\/jats:sub>\n                    Cl(C\n                    <jats:sub>15<\/jats:sub>\n                    H\n                    <jats:sub>22<\/jats:sub>\n                    BN\n                    <jats:sub>6<\/jats:sub>\n                    )(C\n                    <jats:sub>9<\/jats:sub>\n                    H\n                    <jats:sub>27<\/jats:sub>\n                    P\n                    <jats:sub>3<\/jats:sub>\n                    )](C\n                    <jats:sub>24<\/jats:sub>\n                    H\n                    <jats:sub>20<\/jats:sub>\n                    B) or [(Tp*)MoFe\n                    <jats:sub>3<\/jats:sub>\n                    S\n                    <jats:sub>3<\/jats:sub>\n                    (\u03bc\n                    <jats:sub>3<\/jats:sub>\n                    -Cl)(PMe\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    ](BPh\n                    <jats:sub>4<\/jats:sub>\n                    ) [Tp* = tris(3,5-dimethylpyrazol-1-yl)hydro- borate(1-)], crystallizes as block-shaped crystals in space group\n                    <jats:italic>P<\/jats:italic>\n                    <jats:overline>1<\/jats:overline>\n                    . In this cluster, the Mo site is in a distorted octahedral coordination model, coordinating to three N atoms on the Tp* ligand and three \u03bc\n                    <jats:sub>3<\/jats:sub>\n                    -bridging S atoms in the core. The Fe sites adopt a distorted tetrahedral coordination geometry, each coordinating to two \u03bc\n                    <jats:sub>3<\/jats:sub>\n                    -bridging S atoms, one \u03bc\n                    <jats:sub>3<\/jats:sub>\n                    -bridging Cl atom, and the phosphorus atom from a trimethylphosphine ligand. This type of heterometallic and heteroleptic single cubane cluster represents a typical example within the Mo\u2013Fe\u2013S cluster family. It may possess unique advantages in the construction of high-nuclearity clusters, and could serve as a potentially controllable reaction intermediate for the synthesis of FeMo-co mimics. The residual electron density of disordered solvent molecules in the void space could not be reasonably modeled, thus a solvent mask was applied. The solvent contribution is not included in the reported molecular weight and density.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026005475","type":"journal-article","created":{"date-parts":[[2026,6,1]],"date-time":"2026-06-01T14:36:20Z","timestamp":1780324580000},"page":"786-789","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and crystal structure of the cubane-like cluster [(Tp*)MoFe\n                    <sub>3<\/sub>\n                    S\n                    <sub>3<\/sub>\n                    (\u03bc\n                    <sub>3<\/sub>\n                    -Cl)(PMe\n                    <sub>3<\/sub>\n                    )\n                    <sub>3<\/sub>\n                    ](BPh\n                    <sub>4<\/sub>\n                    )"],"prefix":"10.1107","volume":"82","author":[{"given":"Juan","family":"He","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/036trcv74","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuan-Yi","family":"Chen","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/036trcv74","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia","family":"Wei","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/05mxya461","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie","family":"Han","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02zhqgq86","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0152-5410","authenticated-orcid":true,"given":"Xu-Dong","family":"Chen","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/036trcv74","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gan","family":"Xu","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/036trcv74","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,6,5]]},"reference":[{"key":"oi2038_bb1","doi-asserted-by":"crossref","first-page":"11993","DOI":"10.1021\/ja063604x","volume":"128","author":"Berlinguette","year":"2006","journal-title":"J. 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