{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T06:18:15Z","timestamp":1788329895111,"version":"build-2803163510"},"reference-count":24,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2026,5,29]],"date-time":"2026-05-29T00:00:00Z","timestamp":1780012800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,5,29]],"date-time":"2026-05-29T00:00:00Z","timestamp":1780012800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100007684","name":"Ministry of Education and Science of Ukraine","doi-asserted-by":"publisher","award":["0126U001147"],"award-info":[{"award-number":["0126U001147"]}],"id":[{"id":"10.13039\/501100007684","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,5,24]]},"published-print":{"date-parts":[[2026,6,1]]},"abstract":"<jats:p>\n                    In the crystal structure of the title salt, {[Na(H\n                    <jats:sub>2<\/jats:sub>\n                    O)\n                    <jats:sub>3<\/jats:sub>\n                    ](C\n                    <jats:sub>16<\/jats:sub>\n                    H\n                    <jats:sub>11<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    S\n                    <jats:sub>2<\/jats:sub>\n                    )}\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    , the 1-benzyl-[1,2,4]triazolo[1,5-\n                    <jats:italic>c<\/jats:italic>\n                    ]quinazolin-1-ium-2,5-bis(thiolate) anion is not included in the coordination sphere of the sodium cation. The latter is coordinated by five water molecules, two pairs of which form bridges with two neighbouring sodium cations, whilst the fifth water molecule additionally coordinates monodentately. The anion structure can be described as a superposition of two zwitterionic structures with two negative charges located on the sulfur atoms and one positive charge either on the nitrogen nodal atom or on the nitrogen atom bonded to the benzyl group. In the crystal structure, the organic molecules are linked to the aqua ligands\n                    <jats:italic>via<\/jats:italic>\n                    intermolecular O\u2014H...(N,S) hydrogen bonds. The crystal packing can be characterized as layered, defining a three-layer unit parallel to (100) as the main motif. The central part of the three-layer unit consists of\n                    <jats:sup>1<\/jats:sup>\n                    <jats:sub>\u221e<\/jats:sub>\n                    [Na(H\n                    <jats:sub>2<\/jats:sub>\n                    O)\n                    <jats:sub>1\/1<\/jats:sub>\n                    (H\n                    <jats:sub>2<\/jats:sub>\n                    O)\n                    <jats:sub>4\/2<\/jats:sub>\n                    ] chains extending parallel to [010]. Two layers of anion molecules sandwich the cation layer.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026005487","type":"journal-article","created":{"date-parts":[[2026,5,29]],"date-time":"2026-05-29T05:46:36Z","timestamp":1780033596000},"page":"755-759","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Molecular and crystal structure of\n                    <i>catena<\/i>\n                    -poly[1-benzyl-[1,2,4]triazolo[1,5-\n                    <i>c<\/i>\n                    ]quinazolin-1-ium-2,5-bis(thiolate) [[aquasodium]-di-\u03bc-aqua]]"],"prefix":"10.1107","volume":"82","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3946-1061","authenticated-orcid":true,"given":"Svitlana V.","family":"Shishkina","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maryna S.","family":"Kovalenko","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Oleksandr G.","family":"Drushlyak","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9032-6439","authenticated-orcid":true,"given":"Mariia O.","family":"Shyshkina","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/01dr6c206","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7440-4153","authenticated-orcid":true,"given":"Christian","family":"Dank","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2222-8180","authenticated-orcid":true,"given":"Sergiy M.","family":"Kovalenko","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,5,29]]},"reference":[{"key":"wm5796_bb1","doi-asserted-by":"crossref","first-page":"112652","DOI":"10.1016\/j.ejmech.2020.112652","volume":"205","author":"Aggarwal","year":"2020","journal-title":"Eur. 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