{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T20:12:44Z","timestamp":1792786364331,"version":"4.5.0"},"reference-count":27,"publisher":"International Union of Crystallography (IUCr)","issue":"7","license":[{"start":{"date-parts":[[2026,6,26]],"date-time":"2026-06-26T00:00:00Z","timestamp":1782432000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,6,26]],"date-time":"2026-06-26T00:00:00Z","timestamp":1782432000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100018647","name":"RUDN University","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100018647","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Azerbaijan Medical University","id":[{"id":"https:\/\/ror.org\/016a0n751","id-type":"ROR","asserted-by":"crossref"}]},{"name":"Baku Engineering University","id":[{"id":"https:\/\/ror.org\/05wawjf63","id-type":"ROR","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,6,21]]},"published-print":{"date-parts":[[2026,7,1]]},"abstract":"<jats:p>\n                    In the title compound, C\n                    <jats:sub>17<\/jats:sub>\n                    H\n                    <jats:sub>11<\/jats:sub>\n                    BF\n                    <jats:sub>2<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>2<\/jats:sub>\n                    , the molecular conformation is consolidated by an intramolecular C\u2014H...S interaction forming an\n                    <jats:italic>S<\/jats:italic>\n                    (6) ring. In the crystal, molecules are linked by C\u2014H...F interactions, forming a three-dimensional network. The terminal thiophene ring is disordered in a 0.659\u2005(3):0.341\u2005(3) ratio around the C\u2014C bond that connects the thiophene rings, with a rotation of approximately 180\u00b0 around the ring. According to a Hirshfeld surface analysis, H...H (34.8%), C...H\/H...C (22.1%) and F...H\/H...F (18.6%) interactions are the main contributors to the crystal packing.\n                  <\/jats:p>","DOI":"10.1107\/s205698902600647x","type":"journal-article","created":{"date-parts":[[2026,6,23]],"date-time":"2026-06-23T09:49:59Z","timestamp":1782208199000},"page":"871-876","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure and Hirshfeld surface analysis of 10-([2,3\u2032-bithiophen]-5\u2032-yl)-5,5-difluoro-5\n                    <i>H<\/i>\n                    -4\u03bb\n                    <sup>4<\/sup>\n                    ,5\u03bb\n                    <sup>4<\/sup>\n                    -dipyrrolo[1,2-\n                    <i>c<\/i>\n                    :2\u2032,1\u2032-\n                    <i>f<\/i>\n                    ][1,3,2]diazaborinine"],"prefix":"10.1107","volume":"82","author":[{"ORCID":"https:\/\/orcid.org\/0009-0003-2201-7380","authenticated-orcid":true,"given":"Darya K.","family":"Polyanskaya","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-8392-7283","authenticated-orcid":true,"given":"Zlata A.","family":"Polianskaia","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8806-2975","authenticated-orcid":true,"given":"Victor N.","family":"Khrustalev","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2421-0929","authenticated-orcid":true,"given":"Mehmet","family":"Akkurt","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6098-9450","authenticated-orcid":true,"given":"Gizachew Mulugeta","family":"Manahelohe","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Khudayar I.","family":"Hasanov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-4571-9520","authenticated-orcid":true,"given":"Narmina A.","family":"Guliyeva","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,6,26]]},"reference":[{"key":"yz2081_bb1","doi-asserted-by":"crossref","first-page":"1555","DOI":"10.1002\/anie.199515551","volume":"34","author":"Bernstein","year":"1995","journal-title":"Angew. 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