{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T10:03:55Z","timestamp":1790330635833,"version":"4.1.0"},"reference-count":22,"publisher":"International Union of Crystallography (IUCr)","issue":"7","license":[{"start":{"date-parts":[[2026,6,26]],"date-time":"2026-06-26T00:00:00Z","timestamp":1782432000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,6,26]],"date-time":"2026-06-26T00:00:00Z","timestamp":1782432000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,6,22]]},"published-print":{"date-parts":[[2026,7,1]]},"abstract":"<jats:p>\n                    In the search for complexes of the monoorganotin(IV) triiodides,\n                    <jats:italic>R<\/jats:italic>\n                    SnI\n                    <jats:sub>3<\/jats:sub>\n                    , with Lewis bases, LB, a 1:3 complex was was obtained for the first time in the case of isopropyltin(IV) triiodide,\n                    <jats:sup>\n                      <jats:italic>i<\/jats:italic>\n                    <\/jats:sup>\n                    PrSnI\n                    <jats:sub>3<\/jats:sub>\n                    , and LB = pyridine-\n                    <jats:italic>N<\/jats:italic>\n                    -oxide, PyNO. The compound, diiodido(isopropyl)tris(pyridine\n                    <jats:italic>N<\/jats:italic>\n                    -oxide)tin(III) iodide, [Sn(C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>7<\/jats:sub>\n                    )I\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>5<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    NO)\n                    <jats:sub>3<\/jats:sub>\n                    ]I, has an ionic structure and consists of a previously unknown [\n                    <jats:sup>\n                      <jats:italic>i<\/jats:italic>\n                    <\/jats:sup>\n                    PrSn(pyNO)\n                    <jats:sub>3<\/jats:sub>\n                    ]\n                    <jats:sup>+<\/jats:sup>\n                    and an isolated I\n                    <jats:sup>\u2212<\/jats:sup>\n                    ion. The novel cation exhibits a facial arrangement of the PyNO molecules and a\n                    <jats:italic>cis<\/jats:italic>\n                    arrangement of the iodine atoms. In CDCl\n                    <jats:sub>3<\/jats:sub>\n                    , over the course of several weeks, this compound gives rise to a new, second compound, also of ionic structure, containing an triiodidostannate(II) ion, [SnI\n                    <jats:sub>3<\/jats:sub>\n                    ]\n                    <jats:sup>\u2212<\/jats:sup>\n                    , and a solvent molecule in addition to the already known cation, namely, diiodido(isopropyl)tris(pyridine\n                    <jats:italic>N<\/jats:italic>\n                    -oxide)tin(IV) triiodidostannate(II) deuterochloroform monosolvate, [Sn(C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>7<\/jats:sub>\n                    )I\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>5<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    NO)\n                    <jats:sub>3<\/jats:sub>\n                    ][SnI\n                    <jats:sub>3<\/jats:sub>\n                    ]\u00b7CDCl\n                    <jats:sub>3<\/jats:sub>\n                    . The anion exhibits a trigonal\u2013pyramidal structure in order to achieve a stable electron octet at the divalent tin atom but is associated in the crystal\n                    <jats:italic>via<\/jats:italic>\n                    tetrel bonds into one-dimensional chains in which the tin atoms exhibit a 3\n                    <jats:sub>3<\/jats:sub>\n                    -aaa coordination mode.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026006596","type":"journal-article","created":{"date-parts":[[2026,6,24]],"date-time":"2026-06-24T14:52:24Z","timestamp":1782312744000},"page":"888-892","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["From an unusual organotin(IV) coordination compound to the first ionic organic\u2013inorganic mixed-valent tin(IV)\u2013tin(II) compound"],"prefix":"10.1107","volume":"82","author":[{"given":"Daniel","family":"Schwarte","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Swantje","family":"Warf","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Martin","family":"Reichelt","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1251-0783","authenticated-orcid":true,"given":"Hans","family":"Reuter","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,6,26]]},"reference":[{"key":"ox2024_bb1","first-page":"277","volume":"11","author":"Aslanov","year":"1985","journal-title":"Koord. 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