{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,7]],"date-time":"2026-08-07T15:59:55Z","timestamp":1786118395934,"version":"build-2736575974"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T00:00:00Z","timestamp":1784764800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T00:00:00Z","timestamp":1784764800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,7,17]]},"published-print":{"date-parts":[[2026,8,1]]},"abstract":"<jats:p>\n                    The title compound, bis(imidazolidine-2-thione-\u03ba\n                    <jats:italic>S<\/jats:italic>\n                    )dithiocyanatocobalt(II), [Co(NCS)\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    S)\n                    <jats:sub>2<\/jats:sub>\n                    ], was prepared by the reaction of cobalt thiocyanate with ethylenethiourea in ethanol solution. The asymmetric unit (space group\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>c<\/jats:italic>\n                    ) consists of one cobalt cation, as well as two crystallographically independent thiocyanate anions and two ethylenethiourea ligands, all of them located in general positions. The metal cations are tetrahedrally coordinated by two N-bonding anionic ligands and two ethylenethiourea ligands into discrete complexes. These complexes are linked by N\u2014H...S hydrogen bonds into layers. The IR spectrum is in agreement with the presence of a tetrahedral coordination with N-bonding thiocyanate anions and measurements using X-ray powder diffraction indicate that a pure crystalline phase has been obtained. The title compound represents a new isomer of Co(NCS)\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    S)\n                    <jats:sub>2<\/jats:sub>\n                    , which was already reported in the literature in space group\n                    <jats:italic>P<\/jats:italic>\n                    <jats:overline>1<\/jats:overline>\n                    [Mautner\n                    <jats:italic>et al.<\/jats:italic>\n                    , (2018).\n                    <jats:italic>Polyhedron<\/jats:italic>\n                    <jats:bold>154<\/jats:bold>\n                    , 436\u2013442]. In contrast to the title compound, in the triclinic isomer the cobalt cations are octahedrally coordinated and linked into chains by \u03bc-1,3-bridging thiocyanate anions. Solvent-mediated conversion experiments starting from a mixture of both isomers show that the title complex is the thermodynamically stable form at room temperature.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026007383","type":"journal-article","created":{"date-parts":[[2026,7,21]],"date-time":"2026-07-21T09:56:12Z","timestamp":1784627772000},"page":"968-973","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis, crystal structure and stability of a new isomer of bis(ethylenethiourea)dithiocyanatocobalt(II)"],"prefix":"10.1107","volume":"82","author":[{"given":"Christian","family":"N\u00e4ther","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aleksej","family":"Jochim","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,7,23]]},"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2026\/08\/00\/hb8234\/hb8234.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2026\/08\/00\/hb8234\/hb8234.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,6]],"date-time":"2026-08-06T15:46:31Z","timestamp":1786031191000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989026007383"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,23]]},"references-count":0,"journal-issue":{"issue":"8","published-online":{"date-parts":[[2026,8]]}},"alternative-id":["S2056989026007383"],"URL":"https:\/\/doi.org\/10.1107\/s2056989026007383","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989026007383\/hb8234sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989026007383\/hb8234Isup2.hkl","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"value":"2056-9890","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,23]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?hb8234","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"24 June 2026","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"17 July 2026","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"23 July 2026","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?hb8234"}},{"value":"\u00a9 2026 N\u00e4ther and Jochim","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}