{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,7]],"date-time":"2026-08-07T15:59:56Z","timestamp":1786118396598,"version":"build-2736575974"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T00:00:00Z","timestamp":1785456000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T00:00:00Z","timestamp":1785456000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"FF 68","award":["SCI6801309S"],"award-info":[{"award-number":["SCI6801309S"]}]},{"name":"MSc","award":["PSU_GSS 2567-025"],"award-info":[{"award-number":["PSU_GSS 2567-025"]}]},{"DOI":"10.13039\/501100022536","name":"Faculty of Science, Prince of Songkla University","doi-asserted-by":"publisher","award":["364002"],"award-info":[{"award-number":["364002"]}],"id":[{"id":"10.13039\/501100022536","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,7,22]]},"published-print":{"date-parts":[[2026,8,1]]},"abstract":"<jats:p>\n                    The title isomorphous copper(I) coordination complexes, bis(\u03bc-4-methyl-1\n                    <jats:italic>H<\/jats:italic>\n                    -1,2,4-triazole-5-thiolato)bis[chlorido(triphenylphosphane)copper(II)], [Cu\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    N\n                    <jats:sub>3<\/jats:sub>\n                    S)\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>15<\/jats:sub>\n                    P)\n                    <jats:sub>2<\/jats:sub>\n                    ], and bis(\u03bc-4-methyl-1\n                    <jats:italic>H<\/jats:italic>\n                    -1,2,4-triazole-5-thiolato)bis[bromido(triphenylphosphane)copper(II)], [Cu\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    N\n                    <jats:sub>3<\/jats:sub>\n                    S)\n                    <jats:sub>2<\/jats:sub>\n                    Br\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>15<\/jats:sub>\n                    P)\n                    <jats:sub>2<\/jats:sub>\n                    ], were synthesized from copper(I) halide salts and a mixed-ligand system containing Hmptrz and PPh\n                    <jats:sub>3<\/jats:sub>\n                    in acetonitrile (Hmptrz = 4-methyl-1\n                    <jats:italic>H<\/jats:italic>\n                    -1,2,4-triazole-5-thione and PPh\n                    <jats:sub>3<\/jats:sub>\n                    = triphenylphosphine). The asymmetric unit comprises one-half of the dinuclear complex, with each copper(I) center exhibiting a distorted tetrahedral coordination geometry defined by one halide ion, one phosphorus atom from PPh\n                    <jats:sub>3<\/jats:sub>\n                    , and two \u03bc-S bridging from Hmptrz bridging molecules. The two \u03bc-S bridges [Cu\u2014S\u2014Cu \u2243 70.2\u00b0] connect pairs of copper(I) atoms to generate a lozenge-shaped, centrosymmetric Cu\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>2<\/jats:sub>\n                    core. In the extended structure C\u2014H...\n                    <jats:italic>X<\/jats:italic>\n                    (\n                    <jats:italic>X<\/jats:italic>\n                    = Cl or Br) hydrogen bonds link the dimers into a three-dimensional supramolecular architecture. Hirshfeld surface and two-dimensional fingerprint plot analyses were also carried out to investigate and quantify the intermolecular contacts governing the crystal packing.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026007516","type":"journal-article","created":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T08:17:17Z","timestamp":1785485837000},"page":"992-997","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Isomorphous dinuclear copper(I) complexes bridged by 4-methyl-1\n                    <i>H<\/i>\n                    -1,2,4-triazole-5-thiolate ligands: chloride and bromide analogues"],"prefix":"10.1107","volume":"82","author":[{"ORCID":"https:\/\/orcid.org\/0009-0002-3571-4911","authenticated-orcid":true,"given":"Alfandi","family":"Ahmad","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/0575ycz84","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sudthana","family":"Saowanit","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/0575ycz84","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nararak","family":"Leesakul","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/0575ycz84","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pongsaton","family":"Amornpitoksuk","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/0575ycz84","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thitirat","family":"Temram","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/0575ycz84","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thitima","family":"Rujiralai","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/0575ycz84","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0024-9880","authenticated-orcid":true,"given":"Saowanit","family":"Saithong","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/0575ycz84","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,7,31]]},"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2026\/08\/00\/hb8238\/hb8238.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2026\/08\/00\/hb8238\/hb8238.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,6]],"date-time":"2026-08-06T15:46:36Z","timestamp":1786031196000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989026007516"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,31]]},"references-count":0,"journal-issue":{"issue":"8","published-online":{"date-parts":[[2026,8]]}},"alternative-id":["S2056989026007516"],"URL":"https:\/\/doi.org\/10.1107\/s2056989026007516","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989026007516\/hb8238sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989026007516\/hb8238Isup6.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989026007516\/hb8238IIsup7.hkl","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"value":"2056-9890","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,31]]},"assertion":[{"value":"Acta 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2026","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"22 July 2026","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"31 July 2026","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?hb8238"}},{"value":"\u00a9 2026 Ahmad\n                      et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution 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