{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T12:07:33Z","timestamp":1788782853521,"version":"build-2803163510"},"reference-count":33,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2026,8,28]],"date-time":"2026-08-28T00:00:00Z","timestamp":1787875200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,8,28]],"date-time":"2026-08-28T00:00:00Z","timestamp":1787875200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"Rgion Bretagne","award":["ARED-COH24014"],"award-info":[{"award-number":["ARED-COH24014"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,8,12]]},"published-print":{"date-parts":[[2026,9,1]]},"abstract":"<jats:p>\n                    A lanthanum-based complex, heptaaqua(3,4,5,6-tetrabromobenzene-1,2-dicarboxylato)(3,4,5,6-tetrabromo-2-carboxybenzoato)lanthanum(III), [La(C\n                    <jats:sub>8<\/jats:sub>\n                    Br\n                    <jats:sub>4<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    )(C\n                    <jats:sub>8<\/jats:sub>\n                    HBr\n                    <jats:sub>4<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    )(H\n                    <jats:sub>2<\/jats:sub>\n                    O)\n                    <jats:sub>7<\/jats:sub>\n                    ] or [La(tbpa)(Htbpa)(H\n                    <jats:sub>2<\/jats:sub>\n                    O)\n                    <jats:sub>7<\/jats:sub>\n                    ], where H\n                    <jats:sub>2<\/jats:sub>\n                    tbpa is 3,4,5,6-tetrabromophthalic acid, was prepared by microwave-assisted reaction between lanthanum chloride and 3,4,5,6-tetrabromobenzene-1,2-dicarboxylic or tetrabromophthalic acid in water. The La\n                    <jats:sup>3+<\/jats:sup>\n                    is nine-coordinated by seven oxygen atoms from coordinated water molecules and two oxygen atoms from two different ligands in a slightly distorted\n                    <jats:italic>D<\/jats:italic>\n                    <jats:sub>\n                      3\n                      <jats:italic>h<\/jats:italic>\n                    <\/jats:sub>\n                    spherical tricapped trigonal prismatic geometry. The crystal packing features a hydrogen-bonding network and Br...Br interactions.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026008340","type":"journal-article","created":{"date-parts":[[2026,8,14]],"date-time":"2026-08-14T12:00:45Z","timestamp":1786708845000},"page":"1095-1099","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["A lanthanum complex with 3,4,5,6-tetrabromophthalate as ligand"],"prefix":"10.1107","volume":"82","author":[{"given":"Christine","family":"H\u00e9naff","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thierry","family":"Roisnel","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chlo\u00e9","family":"Blais","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Olivier","family":"Guillou","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1038-1017","authenticated-orcid":true,"given":"Carole","family":"Daiguebonne","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,8,28]]},"reference":[{"key":"ee2031_bb1","doi-asserted-by":"crossref","first-page":"1693","DOI":"10.1016\/j.ccr.2005.03.031","volume":"249","author":"Alvarez","year":"2005","journal-title":"Coord. 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