{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T12:07:36Z","timestamp":1788782856085,"version":"build-2803163510"},"reference-count":23,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2026,8,28]],"date-time":"2026-08-28T00:00:00Z","timestamp":1787875200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,8,28]],"date-time":"2026-08-28T00:00:00Z","timestamp":1787875200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,8,21]]},"published-print":{"date-parts":[[2026,9,1]]},"abstract":"<jats:p>\n                    In the title compound, C\n                    <jats:sub>27<\/jats:sub>\n                    H\n                    <jats:sub>28<\/jats:sub>\n                    O\n                    <jats:sub>5<\/jats:sub>\n                    , the aromatic ring of the 4-hexyloxybenzoyl moiety and the central benzoate ring are twisted relative to one another, subtending a dihedral angle of 39.7\u2005(2)\u00b0. The pendant benzyl aromatic ring is nearly orthogonal to the central benzoate ring, forming a dihedral angle of 89.3\u2005(2)\u00b0. The hexyloxy chain adopts an extended, approximately all-\n                    <jats:italic>anti<\/jats:italic>\n                    conformation and two short intramolecular C\u2014H...O contacts are observed. In the extended structure, C\u2014H...\u03c0 interactions help to consolidate the packing. Hirshfeld surface analysis and the corresponding two-dimensional fingerprint plots indicate that H...H contacts constitute the largest contribution to the crystal surface, accounting for 55.4%, followed by C...H\/H...C contacts (22.9%) and O...H\/H...O contacts (16.3%).\n                  <\/jats:p>","DOI":"10.1107\/s2056989026008728","type":"journal-article","created":{"date-parts":[[2026,8,25]],"date-time":"2026-08-25T05:30:46Z","timestamp":1787635846000},"page":"1100-1103","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and structure of benzyl 4-{[4-(hexyloxy)benzoyl]oxy}benzoate"],"prefix":"10.1107","volume":"82","author":[{"given":"P.","family":"Roopadevi","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/012bxv356","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"H. 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