{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,28]],"date-time":"2026-10-28T13:31:18Z","timestamp":1793194278256,"version":"4.5.0"},"reference-count":14,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2026,8,28]],"date-time":"2026-08-28T00:00:00Z","timestamp":1787875200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,8,28]],"date-time":"2026-08-28T00:00:00Z","timestamp":1787875200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,8,23]]},"published-print":{"date-parts":[[2026,9,1]]},"abstract":"<jats:p>\n                    The racemic title compound {systematic name: 2,2-dichloro-\n                    <jats:italic>N<\/jats:italic>\n                    -[(1\n                    <jats:italic>R<\/jats:italic>\n                    ,2\n                    <jats:italic>R<\/jats:italic>\n                    )-1,3-dihydroxy-1-(4-nitrophenyl)propan-2-yl]acetamide}, C\n                    <jats:sub>11<\/jats:sub>\n                    H\n                    <jats:sub>12<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>5<\/jats:sub>\n                    , crystallizes in the space group\n                    <jats:italic>P<\/jats:italic>\n                    <jats:overline>1<\/jats:overline>\n                    . In the crystal, O\u2014H...O, N\u2014H...O and C\u2014H...O hydrogen bonds link the molecules into a three-dimensional architecture, enclosing\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sub>2<\/jats:sub>\n                    (14),\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sub>2<\/jats:sub>\n                    (12),\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sub>2<\/jats:sub>\n                    (10) and\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sup>4<\/jats:sup>\n                    <jats:sub>4<\/jats:sub>\n                    (4) loops. The title compound complements the known orthorhombic form of natural (homochiral) chloramphenicol [Acharya\n                    <jats:italic>et al.<\/jats:italic>\n                    (1979). Acta Cryst. B\n                    <jats:bold>35<\/jats:bold>\n                    , 1360\u20131363], which crystallizes in space group\n                    <jats:italic>C<\/jats:italic>\n                    222\n                    <jats:sub>1<\/jats:sub>\n                    . The Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the crystal packing are from H...O\/O...H (39.4%), H...H (21.7%), H...C\/C...H (15.5%) and Cl...C\/C...Cl (8.3%) interactions.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026008765","type":"journal-article","created":{"date-parts":[[2026,8,25]],"date-time":"2026-08-25T05:32:49Z","timestamp":1787635969000},"page":"1091-1094","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure of racemic chloramphenicol"],"prefix":"10.1107","volume":"82","author":[{"given":"Odil","family":"Choriev","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4441-2803","authenticated-orcid":true,"given":"Jamshid","family":"Ashurov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9218-5596","authenticated-orcid":true,"given":"Batirbay","family":"Torambetov","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8602-4382","authenticated-orcid":true,"given":"Tuncer","family":"H\u00f6kelek","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4175-5656","authenticated-orcid":true,"given":"Alebel N.","family":"Belay","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Khudayar I.","family":"Hasanov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Reyhan Sh.","family":"Hajiyeva","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,8,28]]},"reference":[{"key":"hb8237_bb1","doi-asserted-by":"crossref","first-page":"295","DOI":"10.1007\/BF01200521","volume":"9","author":"Chatterjee","year":"1979","journal-title":"J. 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