{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T11:35:04Z","timestamp":1793100904551,"version":"4.5.0"},"reference-count":35,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100006319","name":"Centre National pour la Recherche Scientifique et Technique","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100006319","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100021856","name":"Ministero dell'Universit\u00e0 e della Ricerca","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100021856","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,8,24]]},"published-print":{"date-parts":[[2026,10,1]]},"abstract":"<jats:p>\n                    In the title compound, C\n                    <jats:sub>21<\/jats:sub>\n                    H\n                    <jats:sub>24<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    OS, are reported. The imidazolone ring is essentially planar, and the coordination geometry about the N-substituted nitrogen atom is also nearly planar, consistent with partial \u03c0-delocalization involving its lone pair. The two phenyl rings are markedly inclined to the imidazolone plane, with dihedral angles of 74.98\u2005(9) and 59.67\u2005(8)\u00b0. In the crystal, weak C\u2014H...O and C\u2014H...\u03c0 interactions contribute to the three-dimensional packing arrangement. Hirshfeld surface analysis shows that H...H contacts dominate the intermolecular interactions, accounting for 68.5% of the surface, followed by C...H\/H...C (19.1%) and O...H\/H...O (6.1%) contacts. A comparison with related structures in the Cambridge Structural Database indicates that the geometric parameters of the heterocyclic core are consistent with those of closely related derivatives.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026008790","type":"journal-article","created":{"date-parts":[[2026,8,26]],"date-time":"2026-08-26T05:46:46Z","timestamp":1787723206000},"page":"1117-1121","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis, crystal structure and Hirshfeld surface analysis of 2-(ethylsulfanyl)-3-(2-methylpropyl)-5,5-diphenyl-4,5-dihydro-3\n                    <i>H<\/i>\n                    -imidazol-4-one"],"prefix":"10.1107","volume":"82","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4846-4547","authenticated-orcid":true,"given":"Abderrazzak","family":"El Moutaouakil Ala Allah","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/00r8w8f84","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0230-1707","authenticated-orcid":true,"given":"Chiara","family":"Massera","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Abdulsalam","family":"Alsubari","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3488-1945","authenticated-orcid":true,"given":"Joel T.","family":"Mague","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6885-5692","authenticated-orcid":true,"given":"Youssef","family":"Ramli","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/00r8w8f84","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,9,3]]},"reference":[{"key":"vm2335_bb1","doi-asserted-by":"crossref","unstructured":"Akrad, R., Guerrab, W., Lazrak, F., Ansar, M. 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