{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T11:35:07Z","timestamp":1793100907508,"version":"4.5.0"},"reference-count":32,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2026,9,8]],"date-time":"2026-09-08T00:00:00Z","timestamp":1788825600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,9,8]],"date-time":"2026-09-08T00:00:00Z","timestamp":1788825600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,8,25]]},"published-print":{"date-parts":[[2026,10,1]]},"abstract":"<jats:p>\n                    The asymmetric unit of the title compound, (3,5-bis{[(4,6-dimethylpyridin-2-yl)amino]methyl}-2,4,6-triethylphenyl)methanol sesquihydrate, C\n                    <jats:sub>29<\/jats:sub>\n                    H\n                    <jats:sub>40<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    O\u00b71.5H\n                    <jats:sub>2<\/jats:sub>\n                    O,\n                    <jats:bold>1<\/jats:bold>\n                    \u00b71.5H\n                    <jats:sub>2<\/jats:sub>\n                    O, contains two crystallographically independent molecules (\n                    <jats:italic>I<\/jats:italic>\n                    and\n                    <jats:italic>II<\/jats:italic>\n                    ) and three water molecules [(\n                    <jats:bold>1<\/jats:bold>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (H\n                    <jats:sub>2<\/jats:sub>\n                    O)\n                    <jats:sub>3<\/jats:sub>\n                    ]. These components are connected by O\u2014H...O and N\u2014H...O hydrogen bonds to form a 2:3 complex. Within this structural unit, the three water molecules and one of the hydroxymethyl O atoms create a strongly distorted eight-membered\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sup>3<\/jats:sup>\n                    (8) supramolecular synthon. In addition, the three water molecules form a structure unit that can be defined as a\n                    <jats:italic>D<\/jats:italic>\n                    3 water cluster. In the crystal, neighbouring 2:3 complexes are linked by N\u2014H...O and O\u2014H...N hydrogen bonds into infinite strand-like aggregates extending along the\n                    <jats:italic>a-<\/jats:italic>\n                    axis direction. The pattern of non-covalent intermolecular bonding is completed by numerous C\u2014H...\u03c0 arene interactions. The crystal contains highly disordered solvent molecules that could not be refined to an acceptable level. Their contribution to the diffraction intensities was therefore removed using the BYPASS routine in\n                    <jats:italic>OLEX2<\/jats:italic>\n                    , and these solvent molecules were excluded from the reported molecular weight and crystal density.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026008856","type":"journal-article","created":{"date-parts":[[2026,8,26]],"date-time":"2026-08-26T05:32:53Z","timestamp":1787722373000},"page":"1149-1153","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of a hydrate of 1,3,5-substituted 2,4,6-trialkylbenzene bearing hydroxymethyl and pyridinylamino groups"],"prefix":"10.1107","volume":"82","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6398-2337","authenticated-orcid":true,"given":"Manuel","family":"Stapf","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wilhelm","family":"Seichter","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3571-7899","authenticated-orcid":true,"given":"Monika","family":"Mazik","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,9,8]]},"reference":[{"key":"jp2032_bb1","doi-asserted-by":"crossref","first-page":"10648","DOI":"10.1039\/C6OB01682K","volume":"14","author":"Amrhein","year":"2016","journal-title":"Org. 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