{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T11:35:03Z","timestamp":1793100903248,"version":"4.5.0"},"reference-count":11,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,8,29]]},"published-print":{"date-parts":[[2026,10,1]]},"abstract":"<jats:p>\n                    The structure of the title compound, C\n                    <jats:sub>7<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    BrO\n                    <jats:sub>3<\/jats:sub>\n                    \u00b7C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>7<\/jats:sub>\n                    NO, at 173\u2005K has triclinic (\n                    <jats:italic>P<\/jats:italic>\n                    <jats:overline>1<\/jats:overline>\n                    ) symmetry with\n                    <jats:italic>Z<\/jats:italic>\n                    = 4. The asymmetric unit comprises two molecules of 5-bromosalicylic acid and two molecules of\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>N<\/jats:italic>\n                    -dimethylformamide (DMF). The crystal structure is dominated by strong O\u2014H...O hydrogen bonds between the carboxylic acid group of the 5-bromosalicylic acid molecules and the carbonyl oxygen atom of the DMF molecules, with the solvent acting as a hydrogen-bond acceptor. This interaction prevents the formation of the common carboxylic acid dimer observed in many benzoic acid derivatives. Additional C\u2014H...O hydrogen bonds and Br...O non-covalent interactions between neighbouring molecules contribute to the cohesion of the structure. Aromatic \u03c0\u2013\u03c0 stacking interactions between adjacent benzene rings further consolidate the crystal structure and generate a three-dimensional supramolecular assembly. Hirshfeld surface analysis confirms that H...H, H...O\/O...H and Br...H\/H...Br contacts make the largest contributions to the crystal packing. The inclusion of DMF therefore plays a significant role in directing the intermolecular interactions and overall supramolecular packing of the crystal structure.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026008984","type":"journal-article","created":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T08:05:28Z","timestamp":1788422728000},"page":"1104-1106","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure and Hirshfeld surface of 5-bromosalicylic acid dimethylformamide monosolvate"],"prefix":"10.1107","volume":"82","author":[{"given":"Oluwatoyin","family":"Akerele","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1569-2831","authenticated-orcid":true,"given":"Andreas","family":"Lemmerer","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,9,3]]},"reference":[{"key":"jp2033_bb1","unstructured":"Bruker (2016). 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Cryst."},{"key":"jp2033_bb8","doi-asserted-by":"crossref","first-page":"5242","DOI":"10.1039\/c2ce25336d","volume":"14","author":"Montis","year":"2012","journal-title":"CrystEngComm"},{"key":"jp2033_bb11","doi-asserted-by":"crossref","first-page":"262","DOI":"10.1107\/S2053229621004460","volume":"77","author":"Roy","year":"2021","journal-title":"Acta Cryst. C"},{"key":"jp2033_bb9","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"jp2033_bb10","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"jp2033_bb15","doi-asserted-by":"crossref","first-page":"1006","DOI":"10.1107\/S1600576721002910","volume":"54","author":"Spackman","year":"2021","journal-title":"J. Appl. Cryst."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2026\/10\/00\/jp2033\/jp2033.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2026\/10\/00\/jp2033\/jp2033.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T11:07:38Z","timestamp":1793099258000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989026008984"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,3]]},"references-count":11,"journal-issue":{"issue":"10","published-online":{"date-parts":[[2026,10]]}},"alternative-id":["S2056989026008984"],"URL":"https:\/\/doi.org\/10.1107\/s2056989026008984","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989026008984\/jp2033sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989026008984\/jp2033Isup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989026008984\/jp2033Isup5.cml","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989026008984\/jp2033sup3.txt","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989026008984\/jp2033sup4.txt","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"value":"2056-9890","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,3]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?jp2033","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"14 August 2026","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"29 August 2026","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"3 September 2026","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?jp2033"}},{"value":"\u00a9 2026 Akerele and Lemmerer","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}