{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T11:35:04Z","timestamp":1793100904118,"version":"4.5.0"},"reference-count":23,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,9,1]]},"published-print":{"date-parts":[[2026,10,1]]},"abstract":"<jats:p>\n                    In the title zinc(II) complex, [Zn(C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>7<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    FN\n                    <jats:sub>2<\/jats:sub>\n                    S)\n                    <jats:sub>2<\/jats:sub>\n                    ], the Zn\n                    <jats:sup>II<\/jats:sup>\n                    atom adopts a tetrahedral coordination geometry (\u03c4\n                    <jats:sub>4<\/jats:sub>\n                    = 0.96), defined by two nitrogen atoms from two neutral 2-amino-6-fluoro-1,3-benzothiazole ligands and two oxygen atoms from two monodentately coordinated acetate anions. The crystal packing is governed by classical N\u2014H...O hydrogen bonds, which generate one-dimensional chains extending along the [011] direction. These chains are further reinforced by bifurcated N\u2014H...(O,F) hydrogen bonds together with C\u2014H...\u03c0, O...\u03c0, and offset \u03c0\u2013\u03c0 interactions, resulting in a robust three-dimensional supramolecular framework. Hirshfeld surface analysis reveals that H...H (31.5%), C...H\/H...C (16.3%), O...H\/H...O (13.0%), F...H\/H...F (12.9%), and S...H\/H...S (10.2%) contacts make the largest contributions to the crystal packing, while a void analysis confirms the efficient packing of the molecules within the crystal.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026009163","type":"journal-article","created":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T16:02:50Z","timestamp":1788364970000},"page":"1126-1131","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis, structure and computational study of diacetatobis(2-amino-6-fluoro-1,3-benzothiazole-\u03ba\n                    <i>N<\/i>\n                    <sup>3<\/sup>\n                    )zinc(II)"],"prefix":"10.1107","volume":"82","author":[{"given":"Dilshoda","family":"Amanova","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zubaydabegim","family":"Radjabova","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-2721-6678","authenticated-orcid":true,"given":"Sardor","family":"Murodov","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0004-2156-2157","authenticated-orcid":true,"given":"Sevinch","family":"Erkinboyeva","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Odil","family":"Choriev","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4441-2803","authenticated-orcid":true,"given":"Jamshid","family":"Ashurov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2606-3221","authenticated-orcid":true,"given":"Shahlo","family":"Daminova","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/011647w73","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,9,3]]},"reference":[{"key":"jp2034_bb1","doi-asserted-by":"crossref","first-page":"11462","DOI":"10.1039\/D2NJ00883A","volume":"46","author":"Akhter","year":"2022","journal-title":"New J. 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