{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T17:53:00Z","timestamp":1791222780572,"version":"4.1.0"},"reference-count":37,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T00:00:00Z","timestamp":1789084800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T00:00:00Z","timestamp":1789084800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,9,4]]},"published-print":{"date-parts":[[2026,10,1]]},"abstract":"<jats:p>\n                    Zinc bis[\n                    <jats:italic>catena<\/jats:italic>\n                    -arsenate(V)] or\n                    <jats:italic>catena<\/jats:italic>\n                    -poly[zinc-di-\u03bc-arsenato(V)-\u03ba\n                    <jats:sup>4<\/jats:sup>\n                    <jats:italic>O<\/jats:italic>\n                    :\n                    <jats:italic>O<\/jats:italic>\n                    ], [Zn(AsO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ]\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    , is isotypic with the low-temperature modification of Zn(PO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    . The asymmetric unit comprises one Zn atom situated on a twofold rotation axis and one As and three O atoms in general positions. In the crystal structure, the principal building units, ZnO\n                    <jats:sub>6<\/jats:sub>\n                    octahedra and AsO\n                    <jats:sub>4<\/jats:sub>\n                    tetrahedra, are condensed into\n                    <jats:sup>1<\/jats:sup>\n                    <jats:sub>\u221e<\/jats:sub>\n                    [ZnO\n                    <jats:sub>4\/2<\/jats:sub>\n                    O\n                    <jats:sub>2\/1<\/jats:sub>\n                    ] zigzag chains and (AsO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    polyarsenate chains with a periodicity of two AsO\n                    <jats:sub>4<\/jats:sub>\n                    tetrahedra, respectively. The two types of chains extend parallel to [001] and are fused into a compact framework structure. Compared with divalent transition metal arsenates and other arsenates of the formula\n                    <jats:italic>M<\/jats:italic>\n                    <jats:sup>II<\/jats:sup>\n                    As\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>6<\/jats:sub>\n                    , Zn(AsO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    is unique in that arsenic is present exclusively in a tetrahedral coordination and not in a mixed tetrahedral\/octahedral or purely octahedral coordination.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026009308","type":"journal-article","created":{"date-parts":[[2026,9,8]],"date-time":"2026-09-08T05:37:45Z","timestamp":1788845865000},"page":"1175-1178","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Zn(AsO\n                    <sub>3<\/sub>\n                    )\n                    <sub>2<\/sub>\n                    , a unique structure among arsenates with composition\n                    <i>M<\/i>\n                    <sup>II<\/sup>\n                    As\n                    <sup>V<\/sup>\n                    <sub>2<\/sub>\n                    O\n                    <sub>6<\/sub>"],"prefix":"10.1107","volume":"82","author":[{"ORCID":"https:\/\/orcid.org\/0009-0009-7149-7310","authenticated-orcid":true,"given":"Maximilian","family":"Pfeiffer","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0087-474X","authenticated-orcid":true,"given":"Berthold","family":"St\u00f6ger","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5235-9910","authenticated-orcid":true,"given":"Matthias","family":"Weil","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,9,11]]},"reference":[{"key":"hb8254_bb1","doi-asserted-by":"crossref","first-page":"15","DOI":"10.1524\/zkri.2006.221.1.15","volume":"221","author":"Aroyo","year":"2006","journal-title":"Z. 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