{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T17:52:56Z","timestamp":1791222776317,"version":"4.1.0"},"reference-count":22,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T00:00:00Z","timestamp":1790726400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T00:00:00Z","timestamp":1790726400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,9,9]]},"published-print":{"date-parts":[[2026,10,1]]},"abstract":"<jats:p>\n                    The 3-imino-3\n                    <jats:italic>H<\/jats:italic>\n                    -isoindol-1-amine tautomeric form of (\n                    <jats:italic>Z<\/jats:italic>\n                    )-\n                    <jats:italic>N<\/jats:italic>\n                    -allyl-3-(allylimino)-3\n                    <jats:italic>H<\/jats:italic>\n                    -isoindol-1-amine, C\n                    <jats:sub>14<\/jats:sub>\n                    H\n                    <jats:sub>15<\/jats:sub>\n                    N\n                    <jats:sub>3<\/jats:sub>\n                    , was confirmed by a single-crystal X-ray diffraction study. The distribution of electron density within the \u2014NH\u2014C=N\u2014C=N\u2014 conjugated fragment corresponds to that found in previously studied\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>N<\/jats:italic>\n                    \u2032-disubstituted 3-imino-3\n                    <jats:italic>H<\/jats:italic>\n                    -isoindol-1-amines. The two molecules in the asymmetric unit of the title compound differ in the conformation of the allyl substituents. In one of these molecules, the two allyl fragments are disordered over two sets of sites in 0.628\u2005(7):0.372\u2005(7) and 0.755\u2005(5):0.245\u2005(5) ratios. In the crystal, the two unique molecules are arranged alternately in infinite chains parallel to [001] due to the formation of intermolecular N\u2014H...N hydrogen bonds.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026009448","type":"journal-article","created":{"date-parts":[[2026,9,10]],"date-time":"2026-09-10T06:42:03Z","timestamp":1789022523000},"page":"1226-1229","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Molecular and crystal structure of (\n                    <i>Z<\/i>\n                    )-\n                    <i>N<\/i>\n                    -allyl-3-(allylimino)-3\n                    <i>H<\/i>\n                    -isoindol-1-amine"],"prefix":"10.1107","volume":"82","author":[{"given":"Volodymyr A.","family":"Tkachuk","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02aaqv166","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3946-1061","authenticated-orcid":true,"given":"Svitlana V.","family":"Shishkina","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4749-7195","authenticated-orcid":true,"given":"Olga V.","family":"Hordiyenko","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02aaqv166","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,9,30]]},"reference":[{"key":"wm5805_bb1","doi-asserted-by":"crossref","first-page":"3836","DOI":"10.1039\/D3DT03950A","volume":"53","author":"Al-Shewiki","year":"2024","journal-title":"Dalton Trans."},{"key":"wm5805_bb2","doi-asserted-by":"crossref","unstructured":"B\u00fcrgi, H.-B. & Dunitz, J. 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