{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T11:35:08Z","timestamp":1793100908896,"version":"4.5.0"},"reference-count":11,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T00:00:00Z","timestamp":1790294400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T00:00:00Z","timestamp":1790294400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,9,15]]},"published-print":{"date-parts":[[2026,10,1]]},"abstract":"<jats:p>\n                    Uranyl(VI) complexes have been researched in many laboratories due to their relevance to actinide coordination chemistry and nuclear fuel reprocessing. The asymmetric unit of the title uranyl complex, [U(C\n                    <jats:sub>5<\/jats:sub>\n                    H\n                    <jats:sub>7<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>5<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )]\u00b70.5CH\n                    <jats:sub>3<\/jats:sub>\n                    OH or [UO\n                    <jats:sub>2<\/jats:sub>\n                    (acac)\n                    <jats:sub>2<\/jats:sub>\n                    (4-amino-3,5-dichloropyridine)]\u00b70.5CH\n                    <jats:sub>3<\/jats:sub>\n                    OH, contains two crystallographically independent uranyl(VI) complex molecules and one methanol solvent molecule. Each U\n                    <jats:sup>VI<\/jats:sup>\n                    atom adopts a UNO\n                    <jats:sub>6<\/jats:sub>\n                    pentagonal\u2013bipyramidal coordination geometry, in which two uranyl O atoms occupy the axial positions, whereas four O atoms from two chelating bidentate acac ligands and one N atom from a 4-amino-3,5-dichloropyridine ligand define the equatorial plane. The U=O bond lengths are 1.757\u2005(10) and 1.807\u2005(11)\u2005\u00c5 for one independent molecule and 1.752\u2005(11) and 1.766\u2005(11)\u2005\u00c5 for the other, while the U=O(acac) and U\u2014N bond lengths lie in the ranges 2.302\u2005(11)\u20132.384\u2005(10)\u2005\u00c5 and 2.591\u2005(13)\u20132.645\u2005(13)\u2005\u00c5, respectively. The bond lengths around the U atoms decrease in the order U\u2014N &gt; U\u2014Oacac &gt; U=O. The uranyl units are slightly bent, with O=U=O angles of 177.0\u2005(5) and 176.5\u2005(5)\u00b0. In the crystal, the methanol solvent molecule is linked to the amino group in the coordinated ligand by an intermolecular N\u2014H...O hydrogen bond [N...O = 2.90\u2005(2)\u2005\u00c5], which is likely to contribute to the low-symmetry crystal arrangement.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026009618","type":"journal-article","created":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T08:13:47Z","timestamp":1790324027000},"page":"1210-1212","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of (4-amino-3,5-dichloropyridine-\u03ba\n                    <i>N<\/i>\n                    <sup>1<\/sup>\n                    )dioxidobis(pentane-2,4-dionato-\u03ba\n                    <sup>2<\/sup>\n                    <i>O<\/i>\n                    ,\n                    <i>O<\/i>\n                    \u2032)uranium(VI) methanol hemisolvate"],"prefix":"10.1107","volume":"82","author":[{"given":"Shogo","family":"Miyazaki","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kosuke","family":"Kitase","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Takeshi","family":"Kawasaki","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Takafumi","family":"Kitazawa","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,9,25]]},"reference":[{"key":"ox2025_bb1","doi-asserted-by":"crossref","first-page":"679","DOI":"10.1039\/dt9840000679","author":"Alcock","year":"1984","journal-title":"J. Chem. Soc. Dalton Trans."},{"key":"ox2025_bb2","unstructured":"Bruker (2025). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"ox2025_bb3","doi-asserted-by":"crossref","first-page":"m673","DOI":"10.1107\/S1600536808009021","volume":"64","author":"Kawasaki","year":"2008","journal-title":"Acta Cryst. E"},{"key":"ox2025_bb4","doi-asserted-by":"crossref","first-page":"m788","DOI":"10.1107\/S1600536808012889","volume":"64","author":"Kawasaki","year":"2008","journal-title":"Acta Cryst. E"},{"key":"ox2025_bb5","doi-asserted-by":"crossref","first-page":"42","DOI":"10.1107\/S2056989014026607","volume":"71","author":"Kawasaki","year":"2015","journal-title":"Acta Cryst. E"},{"key":"ox2025_bb6","doi-asserted-by":"crossref","first-page":"417","DOI":"10.1007\/s10751-006-9302-9","volume":"166","author":"Kawasaki","year":"2006","journal-title":"Hyperfine Interact."},{"key":"ox2025_bb7","doi-asserted-by":"crossref","first-page":"8117","DOI":"10.1021\/acs.inorgchem.5c00189","volume":"64","author":"Kelly","year":"2025","journal-title":"Inorg. Chem."},{"key":"ox2025_bb8","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S1600576714022985","volume":"48","author":"Krause","year":"2015","journal-title":"J. Appl. Cryst."},{"key":"ox2025_bb9","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"ox2025_bb10","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"ox2025_bb11","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2026\/10\/00\/ox2025\/ox2025.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/e\/issues\/2026\/10\/00\/ox2025\/ox2025.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T11:07:54Z","timestamp":1793099274000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989026009618"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,25]]},"references-count":11,"journal-issue":{"issue":"10","published-online":{"date-parts":[[2026,10]]}},"alternative-id":["S2056989026009618"],"URL":"https:\/\/doi.org\/10.1107\/s2056989026009618","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989026009618\/ox2025sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989026009618\/ox2025Isup2.hkl","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"value":"2056-9890","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,25]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?ox2025","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"20 May 2026","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"15 September 2026","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"25 September 2026","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?ox2025"}},{"value":"\u00a9 2026 Miyazaki\n                      et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}