{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T11:35:07Z","timestamp":1793100907516,"version":"4.5.0"},"reference-count":24,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"Government of the Republic of Uzbekistan"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,9,17]]},"published-print":{"date-parts":[[2026,10,1]]},"abstract":"<jats:p>\n                    The crystal structure of the title compound, [Zn(C\n                    <jats:sub>10<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    NO\n                    <jats:sub>3<\/jats:sub>\n                    S)\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>12<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )(H\n                    <jats:sub>2<\/jats:sub>\n                    O)]\u00b7H\n                    <jats:sub>2<\/jats:sub>\n                    O, is reported together with an analysis of its intermolecular interactions. The Zn\n                    <jats:sup>II<\/jats:sup>\n                    ion is five-coordinate, being bonded to two monodentate carboxylate O atoms from two crystallographically independent 3-(2-sulfanylidene-2,3-dihydro-1,3-benzoxazol-3-yl)propanoate ligands, two N atoms of a chelating 1,10-phenanthroline ligand and one water O atom. The coordination geometry is distorted square-pyramidal (\u03c4\n                    <jats:sub>5<\/jats:sub>\n                    \u2243 0.30). Although the two carboxylate ligands adopt the same \u03ba\n                    <jats:italic>O<\/jats:italic>\n                    coordination mode, they differ in their Zn\u2014O bond lengths and in the conformations of their propanoate chains. In the crystal, O\u2014H...O hydrogen bonds involving the coordinated and solvent water molecules link the complexes into one-dimensional ribbons parallel to [100], reinforced by C\u2014H...O and C\u2014H...S contacts. Additional consolidation is provided by \u03c0\u2013\u03c0 stacking interactions involving the phenanthroline and benzoxazoline-derived aromatic rings. Hirshfeld surface analysis shows that H...H (42.0%), H...O\/O...H (19.1%), H...S\/S...H (13.7%) and H...C\/C...H (11.9%) contacts dominate the intermolecular surface, while C...C contacts (5.8%) are consistent with the observed \u03c0\u2013\u03c0 stacking.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026009722","type":"journal-article","created":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T06:53:55Z","timestamp":1790060035000},"page":"1189-1194","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure and Hirshfeld surface analysis of aqua(1,10-phenanthroline-\u03ba\n                    <sup>2<\/sup>\n                    <i>N<\/i>\n                    ,\n                    <i>N<\/i>\n                    \u2032)bis[3-(2-sulfanylidene-2,3-dihydro-1,3-benzoxazol-3-yl)propanoato-\u03ba\n                    <i>O<\/i>\n                    ]zinc(II) monohydrate"],"prefix":"10.1107","volume":"82","author":[{"ORCID":"https:\/\/orcid.org\/0009-0009-5938-6597","authenticated-orcid":true,"given":"Zoxida Rasuljon qizi","family":"Mamadaliyeva","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tulqinjon Abdusattor ogli","family":"Sattarov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Odil Irgashevich","family":"Choriyev","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jalil Tulqin ogli","family":"Qadirov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4441-2803","authenticated-orcid":true,"given":"Jamshid Mengnorovich","family":"Ashurov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,9,22]]},"reference":[{"key":"tx2116_bb1","unstructured":"Agilent (2014). 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