{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T11:35:08Z","timestamp":1793100908265,"version":"4.5.0"},"reference-count":20,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T00:00:00Z","timestamp":1790726400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T00:00:00Z","timestamp":1790726400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,9,17]]},"published-print":{"date-parts":[[2026,10,1]]},"abstract":"<jats:p>\n                    The coordination co-crystal (4-bromo-2-{[(2-hydroxyethyl)imino]methyl}phenololato-\u03ba\n                    <jats:sup>3<\/jats:sup>\n                    <jats:italic>O<\/jats:italic>\n                    ,\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>O<\/jats:italic>\n                    \u2032)(thiocyanato-\u03ba\n                    <jats:italic>N<\/jats:italic>\n                    )copper(II)\u20135-bromo-2-hydroxybenzaldehyde\u2013water (2\/1\/1), [Cu(C\n                    <jats:sub>9<\/jats:sub>\n                    H\n                    <jats:sub>9<\/jats:sub>\n                    BrNO\n                    <jats:sub>2<\/jats:sub>\n                    )(NCS)]\u00b70.5C\n                    <jats:sub>7<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    BrO\n                    <jats:sub>2<\/jats:sub>\n                    \u00b70.5H\n                    <jats:sub>2<\/jats:sub>\n                    O or [Cu(H\n                    <jats:italic>L<\/jats:italic>\n                    )(SCN)]\n                    <jats:sub>2<\/jats:sub>\n                    \u00b7C\n                    <jats:sub>7<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    BrO\n                    <jats:sub>2<\/jats:sub>\n                    \u00b7H\n                    <jats:sub>2<\/jats:sub>\n                    O, crystallizes in the monoclinic space group\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>c<\/jats:italic>\n                    . The asymmetric unit contains two mononuclear units of the complex, each consisting of one deprotonated ligand, one thiocyanate anion (SCN\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) coordinated through its nitrogen atom, one free water molecule, and one free 5-bromosalicylaldehyde molecule, forming a co-crystal. The copper atom is four-coordinate, adopting a slightly distorted square-planar geometry defined by the tridentate ligand and the nitrogen atom of the thiocyanate anion. Bond length values show that the thiocyanate ion has a linear S\u2014C[triple-bond]N arrangement, typical of a terminal, N-bound isothiocyanate group. The water molecule plays a key role in linking the two complex units through O\u2014H...O hydrogen bonds. In the crystal, C\u2014H...O and C\u2014H...Br hydrogen bonds allow the free 5-bromosalicylaldehyde molecule to form a bridge between two adjacent layers. Additional O\u2014H...O, C\u2014H...S, O\u2014H...S, and C\u2014H...N interactions further consolidate the overall structure.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026009746","type":"journal-article","created":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T06:30:02Z","timestamp":1789972202000},"page":"1213-1216","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of a copper complex containing the 4-bromo-2-{[(2-hydroxyethyl)imino]methyl}phenol base Schiff ligand"],"prefix":"10.1107","volume":"82","author":[{"given":"Adama","family":"Niang","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04je6yw13","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Elhadji S\u00e9kou","family":"Mane","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04je6yw13","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5787-3609","authenticated-orcid":true,"given":"Paolo Pio","family":"Mazzeo","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Di\u00e9wo","family":"Ka","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04je6yw13","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ousmane","family":"Diouf","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04je6yw13","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mohamed Lamine","family":"Gaye","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04je6yw13","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4595-8445","authenticated-orcid":true,"given":"Ibrahima Elhadji","family":"Thiam","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04je6yw13","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alessia","family":"Bacchi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,9,30]]},"reference":[{"key":"ex2102_bb1","doi-asserted-by":"crossref","first-page":"3132","DOI":"10.1080\/00958972.2017.1373189","volume":"70","author":"Abbasi","year":"2017","journal-title":"J. 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