{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T11:35:10Z","timestamp":1793100910151,"version":"4.5.0"},"reference-count":14,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T00:00:00Z","timestamp":1790726400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T00:00:00Z","timestamp":1790726400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"Australian Research Council","award":["DP240103289"],"award-info":[{"award-number":["DP240103289"]}],"id":[{"id":"https:\/\/ror.org\/05mmh0f86","id-type":"ROR","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,9,18]]},"published-print":{"date-parts":[[2026,10,1]]},"abstract":"<jats:p>\n                    The title compound, [Ag(C\n                    <jats:sub>6<\/jats:sub>\n                    F\n                    <jats:sub>5<\/jats:sub>\n                    CN)\n                    <jats:sub>4<\/jats:sub>\n                    ][Al{OC(CF\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    }\n                    <jats:sub>4<\/jats:sub>\n                    ], was obtained by reaction of Ag[Al(OC(CF\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>4<\/jats:sub>\n                    ] with excess perfluorobenzonitrile. The crystals belong to the chiral space group\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    with\n                    <jats:italic>Z<\/jats:italic>\n                    \u2032 = 2, containing two independent [Ag(C\n                    <jats:sub>6<\/jats:sub>\n                    F\n                    <jats:sub>5<\/jats:sub>\n                    CN)\n                    <jats:sub>4<\/jats:sub>\n                    ]\n                    <jats:sup>+<\/jats:sup>\n                    cations and two [Al(OC(CF\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>4<\/jats:sub>\n                    ]\n                    <jats:sup>\u2212<\/jats:sup>\n                    anions in the asymmetric unit. Each Ag\n                    <jats:sup>I<\/jats:sup>\n                    centre is four-coordinate and adopts a distorted tetrahedral geometry. One of the nitrile ligands in both Ag\n                    <jats:sup>I<\/jats:sup>\n                    centres has a noticeably longer Ag\u2014N distance [2.383\u2005(8) and 2.371\u2005(9)\u2005\u00c5] and the Ag\u2014N\u2014C angle [148.3\u2005(7) and 148.8\u2005(8)\u00b0] deviates significantly from linearity in both of these cases. The other Ag\u2014N distances are between 2.207\u2005(8) and 2.280\u2005(8)\u2005\u00c5 with Ag\u2014N\u2014C angles between 165.4\u2005(7) and 177.0\u2005(7)\u00b0. N\u2014Ag\u2014N angles vary from 94.5\u2005(3) to 120.3\u2005(3)\u00b0. In the crystallographic overlay, the two Ag\n                    <jats:sup>I<\/jats:sup>\n                    cations appear as approximate non-superimposable mirror images. The arrangement of the cations dominates the crystal packing with the anions occupying the spaces between the cations. There are no short Ag...anion contacts. The structure contains numerous short F...F contacts, which is unsurprising given the perfluorinated nature of the system, and there is an indication of C\u2014F...\u03c0 type interactions.\n                    <jats:sup>19<\/jats:sup>\n                    F NMR spectra of the complex were consistent with the crystallographically determined structure with four perfluorobenzonitrile ligands.\n                  <\/jats:p>","DOI":"10.1107\/s205698902600976x","type":"journal-article","created":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T08:04:31Z","timestamp":1790755471000},"page":"1217-1220","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and crystal structure of tetrakis(perfluorobenzonitrile)silver(I) tetrakis(perfluoro-\n                    <i>tert<\/i>\n                    -butoxy)aluminate(1\u2212): a perfluorinated silver(I) nitrile cation with a perfluorinated weakly coordinating anion"],"prefix":"10.1107","volume":"82","author":[{"ORCID":"https:\/\/orcid.org\/0009-0004-5352-2205","authenticated-orcid":true,"given":"Eric","family":"Wu","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"James D.","family":"Watson","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruoming","family":"Tian","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3693-9063","authenticated-orcid":true,"given":"Mohan","family":"Bhadbhade","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0716-2286","authenticated-orcid":true,"given":"Graham E.","family":"Ball","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,9,30]]},"reference":[{"key":"vu2025_bb1","doi-asserted-by":"crossref","first-page":"321","DOI":"10.1007\/s10870-005-9067-z","volume":"36","author":"Akku\u015f","year":"2006","journal-title":"J. Chem. Crystallogr."},{"key":"vu2025_bb2","unstructured":"Bruker (2024). APEX6 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"vu2025_bb3","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Cryst."},{"key":"vu2025_bb4","doi-asserted-by":"crossref","first-page":"652","DOI":"10.1002\/zaac.201800061","volume":"644","author":"Engesser","year":"2018","journal-title":"Z. Anorg. Allg. Chem."},{"key":"vu2025_bb5","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. B"},{"key":"vu2025_bb6","doi-asserted-by":"crossref","first-page":"1795","DOI":"10.1351\/pac200173111795","volume":"73","author":"Harris","year":"2001","journal-title":"Pure Appl. 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