{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T11:35:10Z","timestamp":1793100910465,"version":"4.5.0"},"reference-count":23,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T00:00:00Z","timestamp":1790294400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T00:00:00Z","timestamp":1790294400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,9,21]]},"published-print":{"date-parts":[[2026,10,1]]},"abstract":"<jats:p>\n                    The asymmetric unit of the title compound, [Co(NCS)\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ]\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    (C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    = pyridine-4-carbonitrile), consists of two crystallographically independent cobalt cations that are located on centers of inversion as well as two independent thiocyanate anions and two independent pyridine-4-carbonitrile coligands that occupy general positions. Each of the cobalt cations is sixfold coordinated by two N- and two S-bonding thiocyanate anions and two pyridine-4-carbonitrile coligands in an slightly distorted CoN\n                    <jats:sub>4<\/jats:sub>\n                    S\n                    <jats:sub>2<\/jats:sub>\n                    octahedral geometry with an all-\n                    <jats:italic>trans<\/jats:italic>\n                    coordination. The cobalt cations are linked by pairs of \u03bc-1,3-bridging anionic ligands into linear chains. Powder X-ray diffraction (PXRD) experiments indicate that the title compound was obtained as a pure phase. Moreover, comparison of the experimental X-ray powder pattern of the residue obtained after water removal from [Co(NCS)\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (H\n                    <jats:sub>2<\/jats:sub>\n                    O)\n                    <jats:sub>2<\/jats:sub>\n                    ] reported recently [N\u00e4ther (2026).\n                    <jats:italic>Acta Cryst.<\/jats:italic>\n                    E\n                    <jats:bold>82<\/jats:bold>\n                    , 441\u2013445] with the calculated powder pattern of the title compound proves that the latter crystalline phase has formed and indicates that a second modification with the same composition as that of the title compound might exist.\n                  <\/jats:p>","DOI":"10.1107\/s2056989026009825","type":"journal-article","created":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T07:16:46Z","timestamp":1790147806000},"page":"1205-1209","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and crystal structure of\n                    <i>catena<\/i>\n                    -poly[[bis(pyridine-4-carbonitrile-\u03ba\n                    <i>N<\/i>\n                    <sup>1<\/sup>\n                    )cobalt(II)]-di-\u03bc-thiocyanato-\u03ba\n                    <sup>2<\/sup>\n                    <i>N<\/i>\n                    :\n                    <i>S<\/i>\n                    ;\u03ba\n                    <sup>2<\/sup>\n                    <i>S<\/i>\n                    :\n                    <i>N<\/i>\n                    ]"],"prefix":"10.1107","volume":"82","author":[{"given":"Christian","family":"N\u00e4ther","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,9,25]]},"reference":[{"key":"hb8260_bb1","unstructured":"Brandenburg, K. 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