{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T11:35:08Z","timestamp":1793100908496,"version":"4.5.0"},"reference-count":24,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T00:00:00Z","timestamp":1790726400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T00:00:00Z","timestamp":1790726400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2026,9,24]]},"published-print":{"date-parts":[[2026,10,1]]},"abstract":"<jats:p>\n                    The title compound, {[CdCl\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ]\u00b7H\n                    <jats:sub>2<\/jats:sub>\n                    O}\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    (C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    = 2,3-dimethylpyrazine) was prepared by the reaction of cadmium chloride with 2,3-dimethylpyrazine in water. The asymmetric unit consists of two crystallographically independent cadmium cations that are situated on a twofold rotation axis, two crystallographically independent chloride anions and 2,3-dimethylpyrazine ligands as well as one water molecule that are all located in general positions. The cadmium cations are octahedrally coordinated by two terminally N-bonded 2,3-dimethylpyrazine ligands and four chloride anions and are linked by pairs of \u03bc-1,1 bridging chloride anions into chains that propagate in the crystallographic\n                    <jats:italic>b<\/jats:italic>\n                    -axis direction. These chains are connected into layers\n                    <jats:italic>via<\/jats:italic>\n                    the water molecule of crystallization by interchain O\u2014H...N hydrogen bonding. Powder X-ray diffraction (PXRD) indicates that a pure phase has been obtained. Thermogravimetry (TG) coupled to differential thermal analysis (DTA) indicates that the water molecules are removed in the first step and that the 2,3-dimethylpyrazine ligands are lost in the subsequent two steps, leading to a compound with the composition [CdCl\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )].\n                  <\/jats:p>","DOI":"10.1107\/s2056989026009941","type":"journal-article","created":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T05:54:10Z","timestamp":1790574850000},"page":"1230-1234","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis, crystal structure and thermal properties of\n                    <i>catena<\/i>\n                    -poly[[[bis(2,3-dimethylpyrazine-\u03ba\n                    <i>N<\/i>\n                    <sup>1<\/sup>\n                    )cadmium(II)]-di-\u03bc-chlorido] monohydrate]"],"prefix":"10.1107","volume":"82","author":[{"given":"Christian","family":"N\u00e4ther","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,9,30]]},"reference":[{"key":"hb8257_bb1","doi-asserted-by":"crossref","first-page":"417","DOI":"10.1016\/0277-5387(96)00312-9","volume":"16","author":"Bailey","year":"1997","journal-title":"Polyhedron"},{"key":"hb8257_bb2","unstructured":"Brandenburg, K. 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