{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,25]],"date-time":"2025-11-25T20:38:02Z","timestamp":1764103082647,"version":"3.33.0"},"reference-count":9,"publisher":"International Union of Crystallography (IUCr)","issue":"4","license":[{"start":{"date-parts":[[2020,4,7]],"date-time":"2020-04-07T00:00:00Z","timestamp":1586217600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2020,4,7]],"date-time":"2020-04-07T00:00:00Z","timestamp":1586217600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2020,3,31]]},"published-print":{"date-parts":[[2020,4,28]]},"abstract":"<jats:p>The asymmetric unit of the binuclear title compound, [Cu<jats:sub>2<\/jats:sub>(C<jats:sub>8<\/jats:sub>H<jats:sub>7<\/jats:sub>O<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>], comprises two halves of diaquatetrakis(\u03bc-3-methoxybenzoato-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>O<\/jats:italic>\n                  <jats:sup>1<\/jats:sup>:<jats:italic>O<\/jats:italic>\n                  <jats:sup>1\u2032<\/jats:sup>)dicopper(II) units. The paddle-wheel structure of each complex is completed by application of inversion symmetry, with the inversion centre situated at the midpoint between two Cu<jats:sup>II<\/jats:sup> atoms in each dimer. The two Cu<jats:sup>II<\/jats:sup> atoms of each centrosymmetric dimer are bridged by four 3-methoxybenzoate anions resulting in Cu...Cu separations of 2.5961\u2005(11) and 2.6060\u2005(12)\u2005\u00c5, respectively. The square-pyramidal coordination sphere of each Cu<jats:sup>II<\/jats:sup> atom is completed by an apical water molecule. Intermolecular O\u2014H...O hydrogen bonds of weak nature link the complexes into layers parallel to (100). The three-dimensional network structure is accomplished by C\u2014H...O hydrogen bonds interlinking adjacent layers.<\/jats:p>","DOI":"10.1107\/s2414314620004484","type":"journal-article","created":{"date-parts":[[2020,4,7]],"date-time":"2020-04-07T10:30:24Z","timestamp":1586255424000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Diaquatetrakis(\u03bc-3-methoxybenzoato-\u03ba<sup>2<\/sup>\n                  <i>O<\/i>\n                  <sup>1<\/sup>:<i>O<\/i>\n                  <sup>1\u2032<\/sup>)dicopper(II)"],"prefix":"10.1107","volume":"5","author":[{"given":"Bikshandarkoil R.","family":"Srinivasan","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Pooja H.","family":"Bhargao","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"P. 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