{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,25]],"date-time":"2025-11-25T20:38:21Z","timestamp":1764103101190,"version":"3.33.0"},"reference-count":9,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2020,6,23]],"date-time":"2020-06-23T00:00:00Z","timestamp":1592870400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2020,6,23]],"date-time":"2020-06-23T00:00:00Z","timestamp":1592870400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100003819","name":"Natural Science Foundation of Hubei Province","doi-asserted-by":"publisher","award":["2014CFB787"],"award-info":[{"award-number":["2014CFB787"]}],"id":[{"id":"10.13039\/501100003819","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2020,6,15]]},"published-print":{"date-parts":[[2020,6,28]]},"abstract":"<jats:p>The title compound, [Cu<jats:sub>2<\/jats:sub>(\u03bc<jats:sub>2<\/jats:sub>-O<jats:sub>2<\/jats:sub>CC<jats:sub>12<\/jats:sub>H<jats:sub>8<\/jats:sub>NO<jats:sub>2<\/jats:sub>S)<jats:sub>4<\/jats:sub>(CH<jats:sub>3<\/jats:sub>CN)<jats:sub>2<\/jats:sub>], consists of a dinuclear and centrosymmetric complex based on two Cu<jats:sup>II<\/jats:sup> atoms coordinated by four 5-nitro-2-phenylsulfanyl-benzoate anions and two acetonitrile ligands. Each benzoate anion acts as a bis-monodentate ligand while each acetonitrile acts as a monodentate ligand, leading to a square-pyramidal NO<jats:sub>4<\/jats:sub> coordination environment for each Cu<jats:sup>II<\/jats:sup> atom with the acetonitrile N atom at the apex. The intramolecular Cu...Cu distance in the dimer is 2.6478\u2005(3)\u2005\u00c5. The cohesion of the crystal structure is ensured by <jats:sub>(phenyl)<\/jats:sub>C\u2014H...O<jats:sub>(nitro)<\/jats:sub> hydrogen bonds and <jats:sub>(phenyl)<\/jats:sub>C\u2014H...\u03c0 interactions.<\/jats:p>","DOI":"10.1107\/s2414314620008019","type":"journal-article","created":{"date-parts":[[2020,6,23]],"date-time":"2020-06-23T07:54:16Z","timestamp":1592898856000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Tetrakis[\u03bc<sub>2<\/sub>-5-nitro-2-(phenylsulfanyl)benzoato-\u03ba<sup>2<\/sup>\n                  <i>O<\/i>:<i>O<\/i>\u2032]bis[(acetonitrile-\u03ba<i>N<\/i>)copper(II)]"],"prefix":"10.1107","volume":"5","author":[{"given":"Danrui","family":"Xu","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jun","family":"Gao","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sihui","family":"Long","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2020,6,23]]},"reference":[{"key":"wm4131_bb1","first-page":"3519","author":"Liu","year":"2007","journal-title":"Synthesis"},{"key":"wm4131_bb2","doi-asserted-by":"crossref","first-page":"226","DOI":"10.1107\/S1600576719014092","volume":"53","author":"Macrae","year":"2020","journal-title":"J. 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