{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,25]],"date-time":"2025-11-25T20:38:28Z","timestamp":1764103108654,"version":"3.37.3"},"reference-count":14,"publisher":"International Union of Crystallography (IUCr)","issue":"7","license":[{"start":{"date-parts":[[2020,7,21]],"date-time":"2020-07-21T00:00:00Z","timestamp":1595289600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2020,7,21]],"date-time":"2020-07-21T00:00:00Z","timestamp":1595289600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2020,7,15]]},"published-print":{"date-parts":[[2020,7,28]]},"abstract":"<jats:p>The title compound, (C<jats:sub>4<\/jats:sub>H<jats:sub>12<\/jats:sub>N)[Cu<jats:sub>3<\/jats:sub>(CN)<jats:sub>4<\/jats:sub>]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, crystallizes as a CuCN network solid, with diethylammonium cations sandwiched between planar CuCN sheets comprised of trigonal planar and digonally coordinated Cu<jats:sup>I<\/jats:sup> atoms bridged by linear CN groups to form 24-membered rings. The digonally coordinated Cu<jats:sup>I<\/jats:sup> atoms and the diethylammonium cations lie on separate crystallographic twofold rotation axes. One of the two independent CN groups has a 50:50 disordered orientation, while the other has one orientation favored due to a N\u2014H...NC hydrogen bond between the diethylammonium cation and the anionic CuCN framework. These hydrogen bonds link the sheets together into a three-dimensional network.<\/jats:p>","DOI":"10.1107\/s2414314620009682","type":"journal-article","created":{"date-parts":[[2020,7,21]],"date-time":"2020-07-21T09:18:44Z","timestamp":1595323124000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Poly[diethylammonium [tetra-\u03bc<sub>2<\/sub>-cyanido-\u03ba<sup>8<\/sup>\n                  <i>C<\/i>:<i>N<\/i>-tricuprate(I)]], a two-dimensional network solid"],"prefix":"10.1107","volume":"5","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9548-5850","authenticated-orcid":true,"given":"Peter W. 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