{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,25]],"date-time":"2025-11-25T20:40:00Z","timestamp":1764103200255,"version":"3.37.3"},"reference-count":23,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2021,6,11]],"date-time":"2021-06-11T00:00:00Z","timestamp":1623369600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2021,6,11]],"date-time":"2021-06-11T00:00:00Z","timestamp":1623369600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2021,6,8]]},"published-print":{"date-parts":[[2021,6,28]]},"abstract":"<jats:p>A new <jats:italic>N<\/jats:italic>-heterocyclic cationic rhodium(I) complex with a tetrafluoridoborate counter-anion, [Rh(C<jats:sub>8<\/jats:sub>H<jats:sub>14<\/jats:sub>N<jats:sub>2<\/jats:sub>)(C<jats:sub>8<\/jats:sub>H<jats:sub>12<\/jats:sub>)(C<jats:sub>18<\/jats:sub>H<jats:sub>15<\/jats:sub>P)]BF<jats:sub>4<\/jats:sub>, has been prepared and structurally characterized. The cationic complex exhibits a distorted square-planar environment around the rhodium(I) ion. Two connections are made from rhodium(I) to the carbon atom of an <jats:italic>N<\/jats:italic>-heterocylic carbene ligand and to the phosphorus atom of a triphenylphosphane ligand. The remaining two coordination sites are made <jats:italic>via<\/jats:italic> a bidentate interaction from the two olefinic bonds of cyclooctadiene to the rhodium(I) ion. The compound includes an out-sphere tetrafluoridoborate counter-anion. Within the crystal of the compound exist several weak intermolecular C\u2014H...F interactions.<\/jats:p>","DOI":"10.1107\/s2414314621005976","type":"journal-article","created":{"date-parts":[[2021,6,11]],"date-time":"2021-06-11T08:56:54Z","timestamp":1623401814000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["[(1,2,5,6-\u03b7)-Cycloocta-1,5-diene](1-ethyl-3-isopropyl-1,3-imidazol-2-ylidene)(triphenylphosphane)rhodium(I) tetrafluoridoborate"],"prefix":"10.1107","volume":"6","author":[{"given":"Jeffrey A.","family":"Rood","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chhatra B.","family":"Subedi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"John P.","family":"Risell","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7957-3674","authenticated-orcid":true,"given":"Andrei V.","family":"Astashkin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Edward","family":"Rajaseelan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2021,6,11]]},"reference":[{"key":"wm4147_bb1","doi-asserted-by":"crossref","first-page":"3596","DOI":"10.1021\/om020338x","volume":"21","author":"Albrecht","year":"2002","journal-title":"Organometallics"},{"key":"wm4147_bb2","unstructured":"Bruker (2013). 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