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The Mn<jats:sup>II<\/jats:sup> cation is coordinated by four pyrrole N atoms (N<jats:sub>p<\/jats:sub>) of the porphyrin ring and one S atom of the apical 4-methylbenzenethiolate ligand with the average Mn\u2014N<jats:sub>p<\/jats:sub> and the apical Mn\u2014S bond lengths being 2.160\u2005(9) and 2.4642\u2005(8)\u2005\u00c5, respectively. Two tetrahydrofuran solvent molecules and a potassium cation chelated inside a [2.2.2]cryptand (4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane) are also present.<\/jats:p>","DOI":"10.1107\/s2414314622002413","type":"journal-article","created":{"date-parts":[[2022,3,10]],"date-time":"2022-03-10T16:19:25Z","timestamp":1646929165000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["([2.2.2]Cryptand)potassium (4-methylbenzenethiolato)[5,10,15,20-tetrakis(4-chlorophenyl)porphyrinato]manganate(II) tetrahydrofuran disolvate"],"prefix":"10.1107","volume":"7","author":[{"given":"Yiwen","family":"Yuan","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jianfeng","family":"Li","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2022,3,8]]},"reference":[{"key":"bt4121_bb1","doi-asserted-by":"crossref","first-page":"476","DOI":"10.1021\/jo01288a053","volume":"32","author":"Adler","year":"1967","journal-title":"J. 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