{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,25]],"date-time":"2025-11-25T20:41:22Z","timestamp":1764103282258,"version":"3.37.3"},"reference-count":13,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2022,3,10]],"date-time":"2022-03-10T00:00:00Z","timestamp":1646870400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2022,3,10]],"date-time":"2022-03-10T00:00:00Z","timestamp":1646870400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100000038","name":"Natural Sciences and Engineering Research Council of Canada","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100000038","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2022,3,3]]},"published-print":{"date-parts":[[2022,3,28]]},"abstract":"<jats:p>The title compound, [Ru<jats:sub>2<\/jats:sub>(\u03bc-O<jats:sub>2<\/jats:sub>CCH<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>(C<jats:sub>5<\/jats:sub>H<jats:sub>4<\/jats:sub>ClN)<jats:sub>2<\/jats:sub>]PF<jats:sub>6<\/jats:sub>\u00b7C<jats:sub>2<\/jats:sub>H<jats:sub>4<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, was obtained <jats:italic>via<\/jats:italic> a rapid substitution reaction of 3-chloropyridine for water in [Ru<jats:sub>2<\/jats:sub>(\u03bc-O<jats:sub>2<\/jats:sub>CCH<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>]PF<jats:sub>6<\/jats:sub> in 2-propanol and subsequent crystallization from a dichloroethane solution. The cationic diruthenium(II,III) tetraacetate core lies on a crystallographic inversion center with Ru\u2014Ru and Ru\u2014N bond lengths of 2.2738\u2005(3) and 2.2920\u2005(17)\u2005\u00c5, respectively. The Ru\u2014Ru\u2014N bond angle is close to linear at 176.48\u2005(4)\u00b0, and a significant \u03c0-stacking interaction of 3.5649\u2005(16)\u2005\u00c5 is seen between overlapping pyridine rings of adjacent cations.<\/jats:p>","DOI":"10.1107\/s2414314622002498","type":"journal-article","created":{"date-parts":[[2022,3,10]],"date-time":"2022-03-10T16:19:25Z","timestamp":1646929165000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Tetra-\u03bc-acetato-\u03ba<sup>8<\/sup>\n                  <i>O<\/i>:<i>O<\/i>\u2032-bis[(3-chloropyridine-\u03ba<i>N<\/i>)ruthenium(II,III)](<i>Ru<\/i>\u2014<i>Ru<\/i>) hexafluoridophosphate 1,2-dichloroethane monosolvate"],"prefix":"10.1107","volume":"7","author":[{"given":"Anthony J.","family":"Aquino","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Daniel","family":"Gerrior","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"T. 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