{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,25]],"date-time":"2025-11-25T20:41:18Z","timestamp":1764103278658,"version":"3.37.3"},"reference-count":14,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2022,3,22]],"date-time":"2022-03-22T00:00:00Z","timestamp":1647907200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2022,3,22]],"date-time":"2022-03-22T00:00:00Z","timestamp":1647907200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100016083","name":"Taishan University","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100016083","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2022,3,16]]},"published-print":{"date-parts":[[2022,3,28]]},"abstract":"<jats:p>In the title complex, [Ni(C<jats:sub>16<\/jats:sub>H<jats:sub>13<\/jats:sub>ClN<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>)(C<jats:sub>3<\/jats:sub>H<jats:sub>4<\/jats:sub>N<jats:sub>2<\/jats:sub>)], the Ni<jats:sup>II<\/jats:sup> ion is coordinated by two O atoms and one N atom derived from the dianionic <jats:italic>N<\/jats:italic>\u2032-[(1<jats:italic>E<\/jats:italic>)-1-(5-chloro-2-hydroxyphenyl)ethylidene]-4-methoxybenzohydrazide ligand and one N atom from the imidazole molecule. The N<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> donor set defines an approximate square-planar geometry. The dihedral angles between the imidazole ring and the fused six-membered and methoxybenzene rings are 17.78\u2005(14) and 13.23\u2005(16)\u00b0, respectively; the dihedral angle between the C<jats:sub>6<\/jats:sub> rings is 6.63\u2005(12)\u00b0. The most prominent feature of the molecular packing is the formation of 4<jats:sub>1<\/jats:sub>-helical chains (along the <jats:italic>c<\/jats:italic> axis) mediated by imidazole-N\u2014H...O(phenoxide) hydrogen bonding; these are linked by methyl-C\u2014H...Cl interactions.<\/jats:p>","DOI":"10.1107\/s2414314622002954","type":"journal-article","created":{"date-parts":[[2022,3,22]],"date-time":"2022-03-22T08:51:08Z","timestamp":1647939068000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["{<i>N<\/i>\u2032-[(<i>E<\/i>)-1-(5-Chloro-2-oxidophenyl)ethylidene]-4-methoxybenzohydrazidato-\u03ba<sup>3<\/sup>\n                  <i>O<\/i>,<i>N<\/i>\u2032,<i>O<\/i>\u2032}(1<i>H<\/i>-imidazole-\u03ba<i>N<\/i>\n                  <sup>3<\/sup>)nickel(II)"],"prefix":"10.1107","volume":"7","author":[{"given":"Jian-Guo","family":"Chang","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2022,3,22]]},"reference":[{"unstructured":"Bruker (2003). 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