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The Mn<jats:sup>III<\/jats:sup> atom has a distorted square-pyramidal environment, being coordinated by four pyrrole N atoms of the porphyrin ligand in the basal plane and an O atom of the nitrato ligand in the apical site. The Mn<jats:sup>III<\/jats:sup> atom is displaced out of the porphyrin plane by 0.22\u2005(4)\u2005\u00c5 with the average Mn\u2014Np distance being 2.011\u2005(6)\u2005\u00c5 (where Np is a porphyrin N atom). The Mn\u2014O bond length is 2.1246\u2005(18)\u2005\u00c5. Two kinds of intermolecular C\u2014H...O hydrogen bonds exist in the crystal structure, with the apical nitrato ligands interacting with solvent molecules and adjacent molecules, respectively.<\/jats:p>","DOI":"10.1107\/s2414314622003868","type":"journal-article","created":{"date-parts":[[2022,4,22]],"date-time":"2022-04-22T08:34:27Z","timestamp":1650616467000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Nitrato(5,10,15,20-tetraphenylporphinato)manganese(III)\u2013benzene\u2013<i>n<\/i>-hexane (2\/1\/1)"],"prefix":"10.1107","volume":"7","author":[{"given":"Hongli","family":"Cao","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Junwen","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jianfeng","family":"Li","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2022,4,22]]},"reference":[{"key":"wm4162_bb1","doi-asserted-by":"crossref","first-page":"2951","DOI":"10.1021\/cr950056p","volume":"96","author":"Averill","year":"1996","journal-title":"Chem. 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