{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,13]],"date-time":"2026-02-13T07:55:51Z","timestamp":1770969351315,"version":"3.50.1"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2022,5,20]],"date-time":"2022-05-20T00:00:00Z","timestamp":1653004800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2022,5,20]],"date-time":"2022-05-20T00:00:00Z","timestamp":1653004800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"Walsh University","award":["2019 Faculty Scholars"],"award-info":[{"award-number":["2019 Faculty Scholars"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2022,5,16]]},"published-print":{"date-parts":[[2022,5,28]]},"abstract":"<jats:p>The structure of the title salt (systematic name: oxodiphenyl-\u03bb<jats:sup>5<\/jats:sup>-iodanylium 4-methylbenzenesulfonate dihydrate), C<jats:sub>12<\/jats:sub>H<jats:sub>10<\/jats:sub>IO<jats:sup>+<\/jats:sup>\u00b7C<jats:sub>7<\/jats:sub>H<jats:sub>7<\/jats:sub>O<jats:sub>3<\/jats:sub>S<jats:sup>\u2212<\/jats:sup>\u00b72H<jats:sub>2<\/jats:sub>O, at 150\u2005K, has monoclinic (<jats:italic>P<\/jats:italic>2<jats:sub>1<\/jats:sub>\/<jats:italic>c<\/jats:italic>) symmetry. The molecular structure features an angular (phenyliodosyl)benzene cation, the geometry of which was hitherto undescribed in the literature: in the cation, both I\u2014C bonds are approximately normal to the I=O bond, forming a C\u2014I\u2014C angle of 95.36\u2005(4)\u00b0. The crystal structure displays O\u2014H...O, O\u2014H...I and O\u2014H...S hydrogen bonding.<\/jats:p>","DOI":"10.1107\/s2414314622005223","type":"journal-article","created":{"date-parts":[[2022,5,20]],"date-time":"2022-05-20T09:28:00Z","timestamp":1653038880000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["(Phenyliodosyl)benzene tosylate dihydrate"],"prefix":"10.1107","volume":"7","author":[{"given":"Timothy J.","family":"Smith","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Gerald","family":"Koser","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yi","family":"Chen","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3305-852X","authenticated-orcid":true,"given":"Matthias","family":"Zeller","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Rocco","family":"Iacino","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5530-5651","authenticated-orcid":true,"given":"Nichole","family":"Selzer","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2022,5,20]]},"container-title":["IUCrData"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/x\/issues\/2022\/05\/00\/bh4069\/bh4069.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/x\/issues\/2022\/05\/00\/bh4069\/bh4069.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T11:08:56Z","timestamp":1736766536000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2414314622005223"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,5,20]]},"references-count":0,"journal-issue":{"issue":"5","published-online":{"date-parts":[[2022,5]]}},"alternative-id":["S2414314622005223"],"URL":"https:\/\/doi.org\/10.1107\/s2414314622005223","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2414314622005223\/bh4069sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2414314622005223\/bh4069Isup3.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2414314622005223\/bh4069Isup3.cml","asserted-by":"subject"}]},"ISSN":["2414-3146"],"issn-type":[{"value":"2414-3146","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,5,20]]},"assertion":[{"value":"IUCrData","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/x"},"group":{"name":"general","label":"General"}},{"value":"data reports","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/x\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?bh4069","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"22 April 2022","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"16 May 2022","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"20 May 2022","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This data article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?bh4069"}},{"value":"\u00a9 2022 Smith et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}],"article-number":"x220522"}}