{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,25]],"date-time":"2025-11-25T20:42:27Z","timestamp":1764103347708,"version":"3.33.0"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2022,10,27]],"date-time":"2022-10-27T00:00:00Z","timestamp":1666828800000},"content-version":"vor","delay-in-days":29,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2022,10,27]],"date-time":"2022-10-27T00:00:00Z","timestamp":1666828800000},"content-version":"tdm","delay-in-days":29,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100009029","name":"Japan Science and Technology Agency, Adaptable and Seamless Technology Transfer Program through Target-Driven R and D","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100009029","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2022,9,26]]},"published-print":{"date-parts":[[2022,9,28]]},"abstract":"<jats:p>The title compound, C<jats:sub>20<\/jats:sub>H<jats:sub>12<\/jats:sub>N<jats:sub>2<\/jats:sub>OS, is a 10-ethynyl-10<jats:italic>H<\/jats:italic>-phenothiazine derivative. The phenothiazine unit has a butterfly shape, where the folding angle between the two benzene rings is 153.87\u2005(7)\u00b0, which is almost as in other reported phenothiazine derivatives. The dihedral angle between the mean plane including the C atoms bonded to the phenothiazine N atom and the benzene ring of the nitrobenzene group is 10.34\u2005(5)\u00b0. The near planar geometry of the molecule is reasonably explained by intramolecular charge-transfer interactions.<\/jats:p>","DOI":"10.1107\/s2414314622009427","type":"journal-article","created":{"date-parts":[[2022,9,27]],"date-time":"2022-09-27T07:45:42Z","timestamp":1664264742000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["10-[(4-Nitrophenyl)ethynyl]-10<i>H<\/i>-phenothiazine"],"prefix":"10.1107","volume":"7","author":[{"given":"Tsunehisa","family":"Okuno","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ikue","family":"Doi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2022,10,27]]},"container-title":["IUCrData"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/x\/issues\/2022\/09\/00\/bh4070\/bh4070.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/x\/issues\/2022\/09\/00\/bh4070\/bh4070.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T11:16:35Z","timestamp":1736766995000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2414314622009427"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,9,28]]},"references-count":0,"journal-issue":{"issue":"9","published-online":{"date-parts":[[2022,9]]}},"alternative-id":["S2414314622009427"],"URL":"https:\/\/doi.org\/10.1107\/s2414314622009427","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2414314622009427\/bh4070sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2414314622009427\/bh4070Isup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2414314622009427\/bh4070Isup3.cml","asserted-by":"subject"}]},"ISSN":["2414-3146"],"issn-type":[{"type":"electronic","value":"2414-3146"}],"subject":[],"published":{"date-parts":[[2022,9,28]]},"assertion":[{"value":"IUCrData","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/x"},"group":{"name":"general","label":"General"}},{"value":"data reports","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/x\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?bh4070","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"13 September 2022","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"26 September 2022","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"27 October 2022","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This data article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?bh4070"}},{"value":"\u00a9 2022 Okuno and Doi","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}],"article-number":"x220942"}}