{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T17:20:32Z","timestamp":1785432032936,"version":"3.56.0"},"reference-count":29,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2023,1,31]],"date-time":"2023-01-31T00:00:00Z","timestamp":1675123200000},"content-version":"vor","delay-in-days":3,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2023,1,31]],"date-time":"2023-01-31T00:00:00Z","timestamp":1675123200000},"content-version":"tdm","delay-in-days":3,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2023,1,24]]},"published-print":{"date-parts":[[2023,1,28]]},"abstract":"<jats:p>\n                    A new triazole-based N-heterocyclic carbene iridium(I) cationic complex with a tetrafluoridoborate counter-anion, [Ir(C\n                    <jats:sub>8<\/jats:sub>\n                    H\n                    <jats:sub>12<\/jats:sub>\n                    )(C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>15<\/jats:sub>\n                    P)(C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>11<\/jats:sub>\n                    N\n                    <jats:sub>3<\/jats:sub>\n                    )]BF\n                    <jats:sub>4<\/jats:sub>\n                    \u00b70.8CH\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    , has been synthesized and structurally characterized. The central Ir\n                    <jats:sup>I<\/jats:sup>\n                    atom of the cationic complex has a distorted square-planar coordination environment, formed by a bidentate cycloocta-1,5-diene (COD) ligand, an N-heterocyclic carbene, and a triphenylphosphane ligand. The crystal structure comprises C\u2014H...\u03c0(ring) interactions that orient the phenyl rings; non-classical hydrogen-bonding interactions between the cationic complex and the tetrafluoridoborate anion are also present. The complex crystallizes in a triclinic unit cell with two structural units and an incorporation of dichloromethane solvate molecules with an occupancy of 0.8.\n                  <\/jats:p>","DOI":"10.1107\/s2414314623000640","type":"journal-article","created":{"date-parts":[[2023,1,31]],"date-time":"2023-01-31T04:14:10Z","timestamp":1675138450000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["[(1,2,5,6-\u03b7)-Cycloocta-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-ylidene)(triphenylphosphane)iridium(I) tetrafluoridoborate dichloromethane 0.8-solvate"],"prefix":"10.1107","volume":"8","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7216-4798","authenticated-orcid":true,"given":"Troy E.","family":"Smith","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03m2x1q45","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrei V.","family":"Astashkin","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03m2x1q45","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4817-3915","authenticated-orcid":true,"given":"Daniel R.","family":"Albert","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02x2aj034","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Edward","family":"Rajaseelan","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02x2aj034","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2023,1,31]]},"reference":[{"key":"wm4181_bb1","doi-asserted-by":"crossref","first-page":"3596","DOI":"10.1021\/om020338x","volume":"21","author":"Albrecht","year":"2002","journal-title":"Organometallics"},{"key":"wm4181_bb2","unstructured":"Bruker (2013). 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