{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,7]],"date-time":"2026-11-07T11:46:18Z","timestamp":1794051978818,"version":"4.8.0"},"reference-count":15,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2023,2,14]],"date-time":"2023-02-14T00:00:00Z","timestamp":1676332800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2023,2,14]],"date-time":"2023-02-14T00:00:00Z","timestamp":1676332800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2023,1,30]]},"published-print":{"date-parts":[[2023,2,28]]},"abstract":"<jats:p>\n                    The crystal-structure determination of the title compound, [RhH(C\n                    <jats:sub>46<\/jats:sub>\n                    H\n                    <jats:sub>44<\/jats:sub>\n                    O\n                    <jats:sub>8<\/jats:sub>\n                    P\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (CO)]\u00b72.25C\n                    <jats:sub>7<\/jats:sub>\n                    D\n                    <jats:sub>8<\/jats:sub>\n                    , is reported. The bisphosphite ligand, C\n                    <jats:sub>46<\/jats:sub>\n                    H\n                    <jats:sub>44<\/jats:sub>\n                    O\n                    <jats:sub>8<\/jats:sub>\n                    P\n                    <jats:sub>2<\/jats:sub>\n                    , is well known as Biphephos. One specific characteristic of this hydrido rhodium(I) monocarbonyl complex is that one bisphosphite ligand is coordinated in the expected bidentate mode and the other is coordinated in a monodentate mode. Thus, one phosphite moiety remains non-coordinating. All three coordinating phosphorus atoms occupy the equatorial positions in the trigonal\u2013bipyramidal environment around the rhodium atom. The crystals of the hydrido rhodium(I) monocarbonyl complex contains deuterated solvent molecules (toluene-\n                    <jats:italic>d<\/jats:italic>\n                    <jats:sub>8<\/jats:sub>\n                    ). Most of them are included in the model, but the contributions of about 0.84 toluene per unit cell were removed from the diffraction data, using the SQUEEZE procedure in\n                    <jats:italic>PLATON<\/jats:italic>\n                    [Spek (2015).\n                    <jats:italic>Acta Cryst.<\/jats:italic>\n                    C\n                    <jats:bold>71<\/jats:bold>\n                    , 9\u201318].\n                  <\/jats:p>","DOI":"10.1107\/s2414314623000834","type":"journal-article","created":{"date-parts":[[2023,2,14]],"date-time":"2023-02-14T04:42:18Z","timestamp":1676349738000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Carbonylbis{6,6\u2032-[(3,3\u2032-di-\n                    <i>tert<\/i>\n                    -butyl-5,5\u2032-dimethoxy-1,1\u2032-biphenyl-2,2\u2032-diyl)bis(oxy)]bis(dibenzo[\n                    <i>d<\/i>\n                    ,\n                    <i>f<\/i>\n                    ][1,3,2]-dioxaphosphepine)}hydridorhodium(I) toluene-\n                    <i>d<\/i>\n                    <sub>8<\/sub>\n                    2.25-solvate"],"prefix":"10.1107","volume":"8","author":[{"given":"Benedict N.","family":"Leidecker","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/029hg0311","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anke","family":"Spannenberg","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/029hg0311","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Robert","family":"Franke","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Armin","family":"B\u00f6rner","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/029hg0311","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christoph","family":"Kubis","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/029hg0311","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2023,2,14]]},"reference":[{"key":"bh4071_bb1","doi-asserted-by":"crossref","unstructured":"B\u00f6rner, A. & Franke, R. (2016). Hydroformylation, Fundamentals, Processes, and Applications in Organic Synthesis. Weinheim: Wiley-VCH.","DOI":"10.1002\/9783527677931"},{"key":"bh4071_bb2","unstructured":"Bruker (2016). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"bh4071_bb3","unstructured":"Bruker (2019). APEX3 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"bh4071_bb4","unstructured":"Leidecker, B. N., Kubis, C., Spannenberg, A., Franke, R. & B\u00f6rner, A. (2019). IUCrData, 4, x191636."},{"key":"bh4071_bb5","doi-asserted-by":"crossref","first-page":"3832","DOI":"10.1021\/om00008a034","volume":"14","author":"Moasser","year":"1995","journal-title":"Organometallics"},{"key":"bh4071_bb6","doi-asserted-by":"crossref","first-page":"4102","DOI":"10.1021\/acs.organomet.5b00538","volume":"34","author":"Mormul","year":"2015","journal-title":"Organometallics"},{"key":"bh4071_bb7","doi-asserted-by":"crossref","first-page":"835","DOI":"10.1021\/om950549k","volume":"15","author":"Rooy","year":"1996","journal-title":"Organometallics"},{"key":"bh4071_bb8","doi-asserted-by":"crossref","first-page":"m488","DOI":"10.1107\/S1600536812011786","volume":"68","author":"Selent","year":"2012","journal-title":"Acta Cryst. E"},{"key":"bh4071_bb9","doi-asserted-by":"crossref","first-page":"m14","DOI":"10.1107\/S1600536812049124","volume":"69","author":"Selent","year":"2013","journal-title":"Acta Cryst. E"},{"key":"bh4071_bb10","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"bh4071_bb11","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"bh4071_bb12","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"bh4071_bb13","doi-asserted-by":"crossref","first-page":"9","DOI":"10.1107\/S2053229614024929","volume":"71","author":"Spek","year":"2015","journal-title":"Acta Cryst. C"},{"key":"bh4071_bb14","doi-asserted-by":"crossref","first-page":"11616","DOI":"10.1021\/ja981969e","volume":"120","author":"Veen","year":"1998","journal-title":"J. Am. Chem. Soc."},{"key":"bh4071_bb15","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."}],"container-title":["IUCrData"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/x\/issues\/2023\/02\/00\/bh4071\/bh4071.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/x\/issues\/2023\/02\/00\/bh4071\/bh4071.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T04:54:41Z","timestamp":1736744081000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2414314623000834"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,2,14]]},"references-count":15,"journal-issue":{"issue":"2","published-online":{"date-parts":[[2023,2]]}},"alternative-id":["S2414314623000834"],"URL":"https:\/\/doi.org\/10.1107\/s2414314623000834","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2414314623000834\/bh4071sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2414314623000834\/bh4071Isup2.hkl","asserted-by":"subject"}]},"ISSN":["2414-3146"],"issn-type":[{"value":"2414-3146","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,2,14]]},"assertion":[{"value":"IUCrData","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/x"},"group":{"name":"general","label":"General"}},{"value":"data reports","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/x\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?bh4071","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"23 November 2022","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"30 January 2023","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"14 February 2023","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This data article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?bh4071"}},{"value":"\u00a9 2023 Leidecker\n                      et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}],"article-number":"x230083"}}