{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T09:44:57Z","timestamp":1736847897772,"version":"3.33.0"},"reference-count":16,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2023,2,17]],"date-time":"2023-02-17T00:00:00Z","timestamp":1676592000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2023,2,17]],"date-time":"2023-02-17T00:00:00Z","timestamp":1676592000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"Publication Fund of the TU Bergakademie Freiberg"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2023,2,8]]},"published-print":{"date-parts":[[2023,2,28]]},"abstract":"<jats:p>The title compound, C<jats:sub>22<\/jats:sub>H<jats:sub>29<\/jats:sub>N<jats:sub>3<\/jats:sub>O<jats:sub>2<\/jats:sub>Si\u00b70.5CHCl<jats:sub>3<\/jats:sub>, crystallizes in the the triclinic space group <jats:italic>P<\/jats:italic>\\overline{1} with two host molecules and one chloroform molecule in the asymmetric unit. The core of the molecule consists of a urea unit bound to a 3-amino-acryloyl group. These units are almost planar in both molecules [average deviation from plane of 0.05\u2005(6)\u2005\u00c5 in molecule <jats:italic>A<\/jats:italic> and 0.04\u2005(5)\u2005\u00c5 in molecule <jats:italic>B<\/jats:italic>]. The main difference between molecules <jats:italic>A<\/jats:italic> and <jats:italic>B<\/jats:italic> involves the dihedral angles of the phenyl groups. One phenyl ring makes dihedral angles of 71.14\u2005(6)\u00b0 (molecule <jats:italic>A<\/jats:italic>) and 82.81\u2005(7)\u00b0 (molecule <jats:italic>B<\/jats:italic>) with respect to the core (C<jats:sub>4<\/jats:sub>N<jats:sub>3<\/jats:sub>O<jats:sub>2<\/jats:sub>) of the molecule [14.56\u2005(9)\u00b0 (molecule <jats:italic>A<\/jats:italic>) and 5.7\u2005(1)\u00b0 (molecule <jats:italic>B<\/jats:italic>) for the other phenyl ring]. Another prominent feature is the intramolecular N\u2014H...O hydrogen bond present in both crystallographically independent molecules.<\/jats:p>","DOI":"10.1107\/s2414314623001177","type":"journal-article","created":{"date-parts":[[2023,2,17]],"date-time":"2023-02-17T07:35:47Z","timestamp":1676619347000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["(<i>E<\/i>)-<i>N<\/i>-Phenyl-<i>N<\/i>-(phenylcarbamoyl)-3-[propyl(trimethylsilyl)amino]acrylamide chloroform hemisolvate"],"prefix":"10.1107","volume":"8","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7537-1840","authenticated-orcid":true,"given":"Marcus","family":"Herbig","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6984-6042","authenticated-orcid":true,"given":"Uwe","family":"B\u00f6hme","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2023,2,17]]},"reference":[{"key":"im4017_bb1","doi-asserted-by":"crossref","first-page":"849","DOI":"10.1107\/S0021889812029111","volume":"45","author":"Farrugia","year":"2012","journal-title":"J. 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