{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T22:25:14Z","timestamp":1740176714444,"version":"3.37.3"},"reference-count":11,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2023,8,1]],"date-time":"2023-08-01T00:00:00Z","timestamp":1690848000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2023,8,1]],"date-time":"2023-08-01T00:00:00Z","timestamp":1690848000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100000038","name":"Natural Sciences and Engineering Research Council of Canada","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100000038","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2023,7,21]]},"published-print":{"date-parts":[[2023,8,28]]},"abstract":"<jats:p>The single-crystal X-ray diffraction structure of the title compound, [SnCl(C<jats:sub>6<\/jats:sub>H<jats:sub>5<\/jats:sub>)<jats:sub>3<\/jats:sub>]\u00b7C<jats:sub>18<\/jats:sub>H<jats:sub>21<\/jats:sub>OP, is reported. The 1:1 cocrystal features a short and directional tetrel bond between tin and oxygen. The tin\u2013oxygen distance is 2.346\u2005(4)\u2005\u00c5, representing 62% of the sum of the van der Waals radii of Sn and O. The Cl\u2014Sn...O angle is 174.0\u2005(1)\u00b0 and this nearly linear arrangement is consistent with a tetrel bond formed <jats:italic>via<\/jats:italic> a \u03c3-hole opposite the tin\u2013chlorine covalent bond. Some weak C\u2014H...Cl interactions are noted between adjacent molecules.<\/jats:p>","DOI":"10.1107\/s2414314623006375","type":"journal-article","created":{"date-parts":[[2023,7,26]],"date-time":"2023-07-26T12:18:26Z","timestamp":1690373906000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Tetrel bond in the triphenyltin(IV) chloride\u2013cyclohexyldiphenylphosphane oxide (1\/1) cocrystal"],"prefix":"10.1107","volume":"8","author":[{"ORCID":"https:\/\/orcid.org\/0009-0000-9075-5391","authenticated-orcid":true,"given":"Sachin","family":"Liyanage","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2114-0443","authenticated-orcid":true,"given":"Jeffrey S.","family":"Ovens","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9989-796X","authenticated-orcid":true,"given":"David L.","family":"Bryce","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2023,8,1]]},"reference":[{"key":"bv4048_bb1","doi-asserted-by":"crossref","first-page":"473","DOI":"10.1002\/tcr.201500256","volume":"16","author":"Bauz\u00e1","year":"2016","journal-title":"Chem. 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