{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T12:15:32Z","timestamp":1785413732277,"version":"3.56.0"},"reference-count":12,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2023,8,10]],"date-time":"2023-08-10T00:00:00Z","timestamp":1691625600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2023,8,10]],"date-time":"2023-08-10T00:00:00Z","timestamp":1691625600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100002470","name":"Dongduk Women's University","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100002470","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2023,8,1]]},"published-print":{"date-parts":[[2023,8,28]]},"abstract":"<jats:p>\n                    In the title compound, C\n                    <jats:sub>22<\/jats:sub>\n                    H\n                    <jats:sub>22<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    , the central pyrazoline ring exhibits a nearly planar structure (r.m.s. deviation = 0.025\u2005\u00c5) despite having two\n                    <jats:italic>sp<\/jats:italic>\n                    <jats:sup>3<\/jats:sup>\n                    carbon atoms. The pyrazoline ring subtends dihedral angles of 4.61\u2005(1) and 87.31\u2005(1)\u00b0 with the pendant benzene ring and naphthalene ring system, respectively. The dihedral angle between the planes of the benzene ring and the naphthalene ring system is 89.76\u2005(2)\u00b0. An intramolecular O\u2014H...N hydrogen bond forms an\n                    <jats:italic>S<\/jats:italic>\n                    (6) ring motif. In the crystal, inversion dimers formed by pairwise weak N\u2014H...N hydrogen bonds generate\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sub>2<\/jats:sub>\n                    (4) loops and the dimers are linked by pairwise C\u2014H...O hydrogen bonds [which generate\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sub>2<\/jats:sub>\n                    (8) loops] into [100] chains.\n                  <\/jats:p>","DOI":"10.1107\/s2414314623006685","type":"journal-article","created":{"date-parts":[[2023,8,4]],"date-time":"2023-08-04T10:04:46Z","timestamp":1691143486000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["2-[5-(2,3-Dimethoxynaphthalen-1-yl)-4,5-dihydro-1\n                    <i>H<\/i>\n                    -pyrazol-3-yl]-3-methoxyphenol"],"prefix":"10.1107","volume":"8","author":[{"given":"Jiha","family":"Sung","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/039p7ck60","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2023,8,10]]},"reference":[{"key":"hb4442_bb1","doi-asserted-by":"crossref","first-page":"96","DOI":"10.1016\/j.ejmech.2015.03.031","volume":"95","author":"Bano","year":"2015","journal-title":"Eur. 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