{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T10:12:12Z","timestamp":1736849532683,"version":"3.33.0"},"reference-count":22,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2023,9,22]],"date-time":"2023-09-22T00:00:00Z","timestamp":1695340800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2023,9,22]],"date-time":"2023-09-22T00:00:00Z","timestamp":1695340800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2023,9,14]]},"published-print":{"date-parts":[[2023,9,28]]},"abstract":"<jats:p>The title compound, [Cr<jats:sub>2<\/jats:sub>(C<jats:sub>2<\/jats:sub>H<jats:sub>3<\/jats:sub>O<jats:sub>2<\/jats:sub>)<jats:sub>4<\/jats:sub>(C<jats:sub>4<\/jats:sub>H<jats:sub>8<\/jats:sub>O)<jats:sub>2<\/jats:sub>] or [Cr<jats:sub>2<\/jats:sub>(OAc)<jats:sub>4<\/jats:sub>(THF)<jats:sub>2<\/jats:sub>] (OAc is acetate, THF is tetrahydrofuran), was obtained by recrystallization of anhydrous chromium(II) acetate [Cr<jats:sub>2<\/jats:sub>(OAc)<jats:sub>4<\/jats:sub>] from hot tetrahydrofuran. The centrosymmetric complex forms monoclinic crystals, space group <jats:italic>C<\/jats:italic>2\/<jats:italic>c<\/jats:italic>, and consists of two Cr<jats:sup>II<\/jats:sup> atoms bridged by four acetate ligands. Additionally, each Cr<jats:sup>II<\/jats:sup> atom is coordinated by a terminal THF ligand, which leads to a square-pyramidal coordination.<\/jats:p>","DOI":"10.1107\/s2414314623008015","type":"journal-article","created":{"date-parts":[[2023,9,18]],"date-time":"2023-09-18T05:11:30Z","timestamp":1695013890000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Tetrakis(\u03bc-acetato-\u03ba<sup>2<\/sup>\n                  <i>O<\/i>:<i>O<\/i>\u2032)bis[(tetrahydrofuran-\u03ba<i>O<\/i>)chromium(II)]"],"prefix":"10.1107","volume":"8","author":[{"ORCID":"https:\/\/orcid.org\/0009-0004-8556-2092","authenticated-orcid":true,"given":"Christian","family":"Heiser","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6349-347X","authenticated-orcid":true,"given":"Kurt","family":"Merzweiler","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2023,9,22]]},"reference":[{"key":"wm4196_bb1","unstructured":"Brandenburg, K. (2019). DIAMOND. Crystal Impact GbR, Bonn, Germany."},{"key":"wm4196_bb2","unstructured":"Coppens, P. (1970). Crystallographic Computing, edited by F. R. Ahmed, S. R. Hall & C. P. Huber, pp. 255-270. Copenhagen: Munksgaard."},{"key":"wm4196_bb3","doi-asserted-by":"crossref","first-page":"1664","DOI":"10.1107\/S0567740871004527","volume":"27","author":"Cotton","year":"1971","journal-title":"Acta Cryst. B"},{"key":"wm4196_bb4","doi-asserted-by":"crossref","first-page":"176","DOI":"10.1021\/ic50179a034","volume":"17","author":"Cotton","year":"1978","journal-title":"Inorg. Chem."},{"key":"wm4196_bb5","doi-asserted-by":"crossref","first-page":"328","DOI":"10.1021\/ic50204a011","volume":"19","author":"Cotton","year":"1980","journal-title":"Inorg. Chem."},{"key":"wm4196_bb6","doi-asserted-by":"crossref","first-page":"416","DOI":"10.1021\/ja993755i","volume":"122","author":"Cotton","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"wm4196_bb7","doi-asserted-by":"crossref","unstructured":"Cotton, F. A., Murillo, C. A. & Walton, R. A. (2005). Multiple Bonds between Metal Atoms, 3rd ed. New York: Springer Science and Business Media Inc.","DOI":"10.1007\/b136230"},{"key":"wm4196_bb8","doi-asserted-by":"crossref","first-page":"4704","DOI":"10.1021\/ja00456a029","volume":"99","author":"Cotton","year":"1977","journal-title":"J. Am. Chem. Soc."},{"key":"wm4196_bb9","doi-asserted-by":"crossref","first-page":"2004","DOI":"10.1021\/ic50185a063","volume":"17","author":"Cotton","year":"1978","journal-title":"Inorg. Chem."},{"key":"wm4196_bb10","doi-asserted-by":"crossref","first-page":"1292","DOI":"10.1021\/ic50218a065","volume":"20","author":"Cotton","year":"1981","journal-title":"Inorg. Chem."},{"key":"wm4196_bb11","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Cryst."},{"key":"wm4196_bb12","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. B"},{"key":"wm4196_bb13","doi-asserted-by":"crossref","first-page":"908","DOI":"10.1039\/C8DT04347G","volume":"48","author":"Huang","year":"2019","journal-title":"Dalton Trans."},{"key":"wm4196_bb14","doi-asserted-by":"crossref","first-page":"6438","DOI":"10.1021\/om300673u","volume":"31","author":"Kulangara","year":"2012","journal-title":"Organometallics"},{"key":"wm4196_bb15","unstructured":"Lange, B. & Vejd\u011blek, Z. J. (1978). Photometrische Analyse, 1st ed. Weinheim, New York: VCH."},{"key":"wm4196_bb16","doi-asserted-by":"crossref","first-page":"501","DOI":"10.1107\/S0365110X53001393","volume":"6","author":"Niekerk","year":"1953","journal-title":"Acta Cryst."},{"key":"wm4196_bb17","first-page":"609","author":"Peligot","year":"1844","journal-title":"C. R. Acad. Sci."},{"key":"wm4196_bb18","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"wm4196_bb19","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"wm4196_bb20","doi-asserted-by":"crossref","first-page":"1006","DOI":"10.1107\/S1600576721002910","volume":"54","author":"Spackman","year":"2021","journal-title":"J. Appl. Cryst."},{"key":"wm4196_bb21","unstructured":"Stoe (2009). X-RED32. Stoe & Cie, Darmstadt, Germany."},{"key":"wm4196_bb22","unstructured":"Stoe (2016). X-AREA. Stoe & Cie, Darmstadt, Germany."}],"container-title":["IUCrData"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/x\/issues\/2023\/09\/00\/wm4196\/wm4196.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/x\/issues\/2023\/09\/00\/wm4196\/wm4196.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T11:27:19Z","timestamp":1736767639000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2414314623008015"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,9,22]]},"references-count":22,"journal-issue":{"issue":"9","published-online":{"date-parts":[[2023,9]]}},"alternative-id":["S2414314623008015"],"URL":"https:\/\/doi.org\/10.1107\/s2414314623008015","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2414314623008015\/wm4196sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2414314623008015\/wm4196Isup2.hkl","asserted-by":"subject"}]},"ISSN":["2414-3146"],"issn-type":[{"type":"electronic","value":"2414-3146"}],"subject":[],"published":{"date-parts":[[2023,9,22]]},"assertion":[{"value":"IUCrData","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/x"},"group":{"name":"general","label":"General"}},{"value":"data reports","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/x\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?wm4196","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"23 August 2023","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"14 September 2023","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"22 September 2023","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This data article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?wm4196"}},{"value":"\u00a9 2023 Heiser and Merzweiler","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}],"article-number":"x230801"}}