{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T09:44:57Z","timestamp":1736847897767,"version":"3.33.0"},"reference-count":8,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2023,9,22]],"date-time":"2023-09-22T00:00:00Z","timestamp":1695340800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2023,9,22]],"date-time":"2023-09-22T00:00:00Z","timestamp":1695340800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/100007508","name":"Lyman Briggs College, Michigan State University","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100007508","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2023,9,16]]},"published-print":{"date-parts":[[2023,9,28]]},"abstract":"<jats:p>The title compound, {[Zn(C<jats:sub>10<\/jats:sub>H<jats:sub>6<\/jats:sub>O<jats:sub>4<\/jats:sub>)(C<jats:sub>16<\/jats:sub>H<jats:sub>16<\/jats:sub>N<jats:sub>4<\/jats:sub>O<jats:sub>2<\/jats:sub>]\u00b72.5H<jats:sub>2<\/jats:sub>O}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, contains five-coordinate Zn<jats:sup>II<\/jats:sup> ions intermediate between square-pyramidal and trigonal\u2013bipyramidal coordination environments. The Zn<jats:sup>II<\/jats:sup> ions are connected by 2-carboxycinnamate (cca) ligands and <jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032-bis-(pyridine-4-carboxamido)piperazine (4-pcap) ligands to construct a non-interpenetrated, tri-periodic coordination polymer with embedded [Zn<jats:sub>2<\/jats:sub>(OCO)<jats:sub>2<\/jats:sub>] dimeric units. Treating these as six-connected nodes reveals an overall (4<jats:sup>12<\/jats:sup>6<jats:sup>3<\/jats:sup>) <jats:bold>pcu<\/jats:bold> topology. One of the 4-pcap piperazinyl rings is disordered equally over two sets of crystallographic positions.<\/jats:p>","DOI":"10.1107\/s2414314623008118","type":"journal-article","created":{"date-parts":[[2023,9,19]],"date-time":"2023-09-19T08:03:06Z","timestamp":1695110586000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Poly[[[\u03bc-1,4-bis(pyridin-4-ylcarbonyl)piperazine-\u03ba<sup>2<\/sup>\n                  <i>N<\/i>:<i>N<\/i>\u2032][\u03bc-2-(2-carboxylatoeth-1-en-1-yl)benzoato-\u03ba<sup>2<\/sup>\n                  <i>O<\/i>:<i>O<\/i>\n                  <sup>2<\/sup>]zinc(II)] 2.5 hydrate]: a tri-periodic coordination polymer with a dimer-based six-connected pcu topology"],"prefix":"10.1107","volume":"8","author":[{"given":"Erika J.","family":"Glatz","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Robert L.","family":"LaDuca","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2023,9,22]]},"reference":[{"key":"tk4097_bb1","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. 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